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Unconventional application of the Mitsunobu reaction: Selective flavonolignan dehydration yielding hydnocarpins

Various Mitsunobu conditions were investigated for a series of flavonolignans (silybin A, silybin B, isosilybin A, and silychristin A) to achieve either selective esterification in position C-23 or dehydration in a one-pot reaction yielding the biologically important enantiomers of hydnocarpin D, hy...

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Detalles Bibliográficos
Autores principales:	Huang, Guozheng, Schramm, Simon, Heilmann, Jörg, Biedermann, David, Křen, Vladimír, Decker, Michael
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901995/ https://www.ncbi.nlm.nih.gov/pubmed/27340458 http://dx.doi.org/10.3762/bjoc.12.66

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