Cargando…

The synthesis of functionalized bridged polycycles via C–H bond insertion

This review presents examples from the chemical literature of syntheses of bridged-polycyclic products via C–H bond insertion by carbenes and nitrenes. Applications to natural product synthesis, a description of the essential elements in substrate-controlled reactions, and mechanistic details of tra...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shih, Jiun-Le, Chen, Po-An, May, Jeremy A
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902037/ https://www.ncbi.nlm.nih.gov/pubmed/27340489 http://dx.doi.org/10.3762/bjoc.12.97

Ejemplares similares

Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C–H bond insertion cascades
por: Shih, Jiun-Le, et al.
Publicado: (2017)

A Case for Bond‐Network Analysis in the Synthesis of Bridged Polycyclic Complex Molecules: Hetidine and Hetisine Diterpenoid Alkaloids
por: Doering, Nicolle A., et al.
Publicado: (2020)

Recent advances in C(sp(3))–H bond functionalization via metal–carbene insertions
por: Wang, Bo, et al.
Publicado: (2016)

Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage
por: Okorn, Alexander, et al.
Publicado: (2022)

Dual C–H Functionalization of N-Aryl Amines: Synthesis of Polycyclic Amines via an Oxidative Povarov Approach
por: Min, Chang, et al.
Publicado: (2014)

Isocyanate-Free Polyurea Synthesis via Ru-Catalyzed Carbene Insertion into the N–H Bonds of Urea
por: de Zwart, Felix J., et al.
Publicado: (2022)

Enantioselective carbenoid insertion into C(sp(3))–H bonds
por: Santiago, J V, et al.
Publicado: (2016)

Adsorption of Polycyclic Aromatic Hydrocarbons and C(60) onto Forsterite: C–H Bond Activation by the Schottky Vacancy
por: Campisi, Dario, et al.
Publicado: (2022)

Hydrogen bridges of polycyclic aromatic systems with O-H···O bonds — a gas-phase vs. solid-state Car-Parrinello study
por: Panek, Jarosław J., et al.
Publicado: (2015)

Synthesis of Di-, Tri-, and Tetrasubstituted Oxetanes by Rhodium-Catalyzed O=H Insertion and C=C Bond-Forming Cyclization**
por: Davis, Owen A, et al.
Publicado: (2014)

From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp(3))–H Bond
por: Chi, Huiwen, et al.
Publicado: (2019)

Metal-free tandem carbene N–H insertions and C–C bond cleavages
por: Chen, Pu, et al.
Publicado: (2020)

Enantioselective Synthesis of α-Trifluoromethyl Amines via Biocatalytic N–H Bond Insertion with Acceptor-Acceptor Carbene Donors
por: Nam, Donggeon, et al.
Publicado: (2022)

Artificial Metalloenzyme-Catalyzed Enantioselective Amidation via Nitrene Insertion in Unactivated C(sp(3))–H Bonds
por: Yu, Kun, et al.
Publicado: (2023)

Synthesis of Polycyclic Imidazolidinones via Amine Redox-Annulation
por: Zhu, Zhengbo, et al.
Publicado: (2017)

Disulfide Bond Bridge Insertion Turns Hydrophobic Anticancer Prodrugs into Self-Assembled Nanomedicines
por: Wang, Yongjun, et al.
Publicado: (2014)

Recent Advances in the Synthesis of Cyclic Sulfoximines via C–H Bond Activation
por: Wang, Bingren, et al.
Publicado: (2023)

Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization
por: Wangweerawong, Apiwat, et al.
Publicado: (2014)

An Approach to the Synthesis of Functionalized Polycyclic Aromatic Hydrocarbons
por: Little, Mark, et al.
Publicado: (2013)

Hydantoin-bridged medium ring scaffolds by migratory insertion of urea-tethered nitrile anions into aromatic C–N bonds
por: Millward, Makenzie J., et al.
Publicado: (2020)

Site-selective functionalization of remote aliphatic C–H bonds via C–H metallation
por: Zhang, Qi, et al.
Publicado: (2020)

Asymmetric formal C–C bond insertion into aldehydes via copper-catalyzed diyne cyclization
por: Li, Cui-Ting, et al.
Publicado: (2023)

Synthesis of unsymmetrically and symmetrically functionalized disiloxanes via subsequent hydrosilylation of C≡C bonds
por: Szyling, Jakub, et al.
Publicado: (2023)

Facile synthesis of polycyclic metallaarynes
por: Ruan, Wenqing, et al.
Publicado: (2018)

Photocatalytic Synthesis of Polycyclic Indolones
por: Saget, Tanguy, et al.
Publicado: (2020)

Silver-Exchanged Zeolite Y Catalyzes a Selective Insertion of Carbenes into C–H and O–H Bonds
por: Zheng, Yongkun, et al.
Publicado: (2023)

Identification of diborane(4) with bridging B–H–B bonds
por: Chou, Sheng-Lung, et al.
Publicado: (2015)

Divergent stereochemical outcomes in the insertion of donor/donor carbenes into the C–H bonds of stereogenic centers
por: Dishman, Sarah N., et al.
Publicado: (2021)

Synthesis of 1H-Indazoles via Silver(I)-Mediated Intramolecular Oxidative C–H Bond Amination
por: Park, Areum, et al.
Publicado: (2021)

Enantioselective carbene insertion into the N–H bond of benzophenone imine
por: Yang, Jian, et al.
Publicado: (2019)

Visible-light-induced indole synthesis via intramolecular C–N bond formation: desulfonylative C(sp(2))–H functionalization
por: Li, Quanzhe, et al.
Publicado: (2022)

Migratory Insertion of Carbenes into Au(III)–C Bonds
por: Zhukhovitskiy, Aleksandr V., et al.
Publicado: (2017)

Migratory Insertion of CO into a Au–C Bond
por: Cadge, Jamie A., et al.
Publicado: (2022)

Highly Deformed o‐Carborane Functionalised Non‐linear Polycyclic Aromatics with Exceptionally Long C−C Bonds
por: Marsh, Adam V., et al.
Publicado: (2020)

Modular Synthesis of Polycyclic Alkaloid Scaffolds via an Enantioselective Dearomative Cascade
por: Rossi-Ashton, James A., et al.
Publicado: (2020)

Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture
por: Lian, Yajing, et al.
Publicado: (2013)

Modular Synthesis of Highly Substituted 3-Azapyrroles by Rh(II)-Catalyzed N–H Bond Insertion and Cyclodehydration
por: Williams, Matthew B., et al.
Publicado: (2022)

Synthesis of Polycyclic Hetero-Fused 7-Deazapurine Heterocycles and Nucleosides through C–H Dibenzothiophenation and Negishi Coupling
por: Yang, Chao, et al.
Publicado: (2022)

Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization
por: Speelman, Amy L., et al.
Publicado: (2021)

Synthesis of 2-Cyanobenzothiazoles via Pd-Catalyzed/Cu-Assisted C-H Functionalization/Intramolecular C-S Bond Formation from N-Arylcyanothioformamides †
por: Broudic, Nathan, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_jf52495dakisu733osmv08g31i