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Enantioselective carbenoid insertion into C(sp(3))–H bonds

The enantioselective carbenoid insertion into C(sp(3))–H bonds is an important tool for the synthesis of complex molecules due to the high control of enantioselectivity in the formation of stereogenic centers. This paper presents a brief review of the early issues, related mechanistic studies and re...

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Detalles Bibliográficos
Autores principales: Santiago, J V, Machado, A H L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902057/
https://www.ncbi.nlm.nih.gov/pubmed/27340479
http://dx.doi.org/10.3762/bjoc.12.87
Descripción
Sumario:The enantioselective carbenoid insertion into C(sp(3))–H bonds is an important tool for the synthesis of complex molecules due to the high control of enantioselectivity in the formation of stereogenic centers. This paper presents a brief review of the early issues, related mechanistic studies and recent applications on this chemistry area.