1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis

Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility an...

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Detalles Bibliográficos
Autores principales: Mielgo, Antonia, Palomo, Claudio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902076/
https://www.ncbi.nlm.nih.gov/pubmed/27340482
http://dx.doi.org/10.3762/bjoc.12.90
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author Mielgo, Antonia
Palomo, Claudio
author_facet Mielgo, Antonia
Palomo, Claudio
author_sort Mielgo, Antonia
collection PubMed
description Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions.
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spelling pubmed-49020762016-06-23 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis Mielgo, Antonia Palomo, Claudio Beilstein J Org Chem Review Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions. Beilstein-Institut 2016-05-09 /pmc/articles/PMC4902076/ /pubmed/27340482 http://dx.doi.org/10.3762/bjoc.12.90 Text en Copyright © 2016, Mielgo and Palomo https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Mielgo, Antonia
Palomo, Claudio
1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title_full 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title_fullStr 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title_full_unstemmed 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title_short 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
title_sort 1h-imidazol-4(5h)-ones and thiazol-4(5h)-ones as emerging pronucleophiles in asymmetric catalysis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902076/
https://www.ncbi.nlm.nih.gov/pubmed/27340482
http://dx.doi.org/10.3762/bjoc.12.90
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