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Ambiphilic boron in 1,4,2,5-diazadiborinine

Boranes have long been known as the archetypal Lewis acids owing to an empty p-orbital on the boron centre. Meanwhile, Lewis basic tricoordinate boranes have been developed in recent years. Here we report the synthesis of an annulated 1,4,2,5-diazadiborinine derivative featuring boron atoms that exh...

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Detalles Bibliográficos
Autores principales: Wang, Baolin, Li, Yongxin, Ganguly, Rakesh, Hirao, Hajime, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906229/
https://www.ncbi.nlm.nih.gov/pubmed/27279265
http://dx.doi.org/10.1038/ncomms11871