Cargando…
Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combi...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906490/ http://dx.doi.org/10.1002/open.201600004 |
_version_ | 1782437423464054784 |
---|---|
author | Duran, Josep Polo, Alfonso Real, Julio Benet‐Buchholz, Jordi Solà, Miquel Poater, Albert |
author_facet | Duran, Josep Polo, Alfonso Real, Julio Benet‐Buchholz, Jordi Solà, Miquel Poater, Albert |
author_sort | Duran, Josep |
collection | PubMed |
description | The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combined with density functional theory (DFT) calculations to rationalize the reaction mechanistically and through conceptual DFT. The exciting point of this study is that it opens the door to test new experimental pathways to monitor the preferred cis or trans arrangement of bidentate ligands to platinum. (Legend: H‐white, C‐black, P‐purple, S‐yellow, Cl‐green, Pt‐blue.) More information can be found in the Full Paper by Alfonso Polo, Albert Poater et al. on page 51 in Issue 1, 2016 (DOI: 10.1002/open.201500136).[Image: see text] |
format | Online Article Text |
id | pubmed-4906490 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-49064902016-06-15 Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) Duran, Josep Polo, Alfonso Real, Julio Benet‐Buchholz, Jordi Solà, Miquel Poater, Albert ChemistryOpen Cover Pictures The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combined with density functional theory (DFT) calculations to rationalize the reaction mechanistically and through conceptual DFT. The exciting point of this study is that it opens the door to test new experimental pathways to monitor the preferred cis or trans arrangement of bidentate ligands to platinum. (Legend: H‐white, C‐black, P‐purple, S‐yellow, Cl‐green, Pt‐blue.) More information can be found in the Full Paper by Alfonso Polo, Albert Poater et al. on page 51 in Issue 1, 2016 (DOI: 10.1002/open.201500136).[Image: see text] John Wiley and Sons Inc. 2016-02-03 /pmc/articles/PMC4906490/ http://dx.doi.org/10.1002/open.201600004 Text en © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
spellingShingle | Cover Pictures Duran, Josep Polo, Alfonso Real, Julio Benet‐Buchholz, Jordi Solà, Miquel Poater, Albert Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title | Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title_full | Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title_fullStr | Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title_full_unstemmed | Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title_short | Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) |
title_sort | cover picture: structural preferences in phosphanylthiolato platinum(ii) complexes (chemistryopen 1/2016) |
topic | Cover Pictures |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906490/ http://dx.doi.org/10.1002/open.201600004 |
work_keys_str_mv | AT duranjosep coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 AT poloalfonso coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 AT realjulio coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 AT benetbuchholzjordi coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 AT solamiquel coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 AT poateralbert coverpicturestructuralpreferencesinphosphanylthiolatoplatinumiicomplexeschemistryopen12016 |