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Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)

The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combi...

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Autores principales: Duran, Josep, Polo, Alfonso, Real, Julio, Benet‐Buchholz, Jordi, Solà, Miquel, Poater, Albert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906490/
http://dx.doi.org/10.1002/open.201600004
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author Duran, Josep
Polo, Alfonso
Real, Julio
Benet‐Buchholz, Jordi
Solà, Miquel
Poater, Albert
author_facet Duran, Josep
Polo, Alfonso
Real, Julio
Benet‐Buchholz, Jordi
Solà, Miquel
Poater, Albert
author_sort Duran, Josep
collection PubMed
description The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combined with density functional theory (DFT) calculations to rationalize the reaction mechanistically and through conceptual DFT. The exciting point of this study is that it opens the door to test new experimental pathways to monitor the preferred cis or trans arrangement of bidentate ligands to platinum. (Legend: H‐white, C‐black, P‐purple, S‐yellow, Cl‐green, Pt‐blue.) More information can be found in the Full Paper by Alfonso Polo, Albert Poater et al. on page 51 in Issue 1, 2016 (DOI: 10.1002/open.201500136).[Image: see text]
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spelling pubmed-49064902016-06-15 Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016) Duran, Josep Polo, Alfonso Real, Julio Benet‐Buchholz, Jordi Solà, Miquel Poater, Albert ChemistryOpen Cover Pictures The cover picture shows phosphanylthiolate ligand coordination on a platinum(II) center to give only the bischelate cis‐P,P isomer when the ligand/Pt ratio is 2, whereas a trinuclear unexpected complex is achieved with a ligand/Pt ratio of 1. Here, the synthesis and structural determination is combined with density functional theory (DFT) calculations to rationalize the reaction mechanistically and through conceptual DFT. The exciting point of this study is that it opens the door to test new experimental pathways to monitor the preferred cis or trans arrangement of bidentate ligands to platinum. (Legend: H‐white, C‐black, P‐purple, S‐yellow, Cl‐green, Pt‐blue.) More information can be found in the Full Paper by Alfonso Polo, Albert Poater et al. on page 51 in Issue 1, 2016 (DOI: 10.1002/open.201500136).[Image: see text] John Wiley and Sons Inc. 2016-02-03 /pmc/articles/PMC4906490/ http://dx.doi.org/10.1002/open.201600004 Text en © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Pictures
Duran, Josep
Polo, Alfonso
Real, Julio
Benet‐Buchholz, Jordi
Solà, Miquel
Poater, Albert
Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title_full Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title_fullStr Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title_full_unstemmed Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title_short Cover Picture: Structural Preferences in Phosphanylthiolato Platinum(II) Complexes (ChemistryOpen 1/2016)
title_sort cover picture: structural preferences in phosphanylthiolato platinum(ii) complexes (chemistryopen 1/2016)
topic Cover Pictures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906490/
http://dx.doi.org/10.1002/open.201600004
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