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Ceria–Vanadia/Silica‐Catalyzed Cascade for C−C and C−O Bond Activation: Green One‐Pot Synthesis of 2‐Amino‐3‐cyano‐4H‐pyrans

We designed a ceria–vanadia/silica (Ce–V/SiO(2)) heterogeneous catalyst and used it for the green and efficient synthesis of 2‐amino‐3‐cyano‐4H‐pyran derivatives. The green reaction was a multicomponent one‐pot condensation of 5,5‐dimethylcyclohexane‐1,3‐dione, aromatic aldehyde, and malononitrile i...

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Detalles Bibliográficos
Autores principales: Maddila, Surya Narayana, Maddila, Suresh, van Zyl, Werner E., Jonnalagadda, Sreekantha B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4906492/
https://www.ncbi.nlm.nih.gov/pubmed/27308209
http://dx.doi.org/10.1002/open.201500159