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Crystal structure and Hirshfeld surface analysis of (E)-3-(2-chloro-6-fluoro­phen­yl)-1-(3-fluoro-4-meth­oxy­phen­yl)prop-2-en-1-one

In the title chalcone derivative, C(16)H(11)ClF(2)O(2), the enone group adopts an E conformation. The dihedral angle between the benzene rings is 0.47 (9)° and an intra­molecular C—H⋯F hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked into a three-dimensional network by C—H⋯O...

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Detalles Bibliográficos
Autores principales: Hassan, Nur Hafiq Hanif, Abdullah, Amzar Ahlami, Arshad, Suhana, Khalib, Nuridayanti Che, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908511/
https://www.ncbi.nlm.nih.gov/pubmed/27308026
http://dx.doi.org/10.1107/S2056989016006526
Descripción
Sumario:In the title chalcone derivative, C(16)H(11)ClF(2)O(2), the enone group adopts an E conformation. The dihedral angle between the benzene rings is 0.47 (9)° and an intra­molecular C—H⋯F hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds and aromatic π–π stacking inter­actions are also observed [centroid–centroid separation = 3.5629 (18) Å]. The inter­molecular inter­actions in the crystal structure were qu­anti­fied and analysed using Hirshfeld surface analysis.