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Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene
The title compound, C(30)H(29)NO(4), is a tetracyclic system containing a 4-arylpyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methylphenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benze...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908512/ https://www.ncbi.nlm.nih.gov/pubmed/27308014 http://dx.doi.org/10.1107/S2056989016005752 |
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author | Tran, T. Thanh Van Anh, Le Tuan Nguyen, Hung Huy Truong, Hong Hieu Soldatenkov, Anatoly T. |
author_facet | Tran, T. Thanh Van Anh, Le Tuan Nguyen, Hung Huy Truong, Hong Hieu Soldatenkov, Anatoly T. |
author_sort | Tran, T. Thanh Van |
collection | PubMed |
description | The title compound, C(30)H(29)NO(4), is a tetracyclic system containing a 4-arylpyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methylphenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benzene rings. The benzene rings are inclined to one another by 88.32 (6)°. In the crystal, molecules are linked by pairs of C—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via a number of C—H⋯π interactions, forming a three-dimensional architecture. |
format | Online Article Text |
id | pubmed-4908512 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49085122016-06-15 Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene Tran, T. Thanh Van Anh, Le Tuan Nguyen, Hung Huy Truong, Hong Hieu Soldatenkov, Anatoly T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(30)H(29)NO(4), is a tetracyclic system containing a 4-arylpyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methylphenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benzene rings. The benzene rings are inclined to one another by 88.32 (6)°. In the crystal, molecules are linked by pairs of C—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via a number of C—H⋯π interactions, forming a three-dimensional architecture. International Union of Crystallography 2016-04-12 /pmc/articles/PMC4908512/ /pubmed/27308014 http://dx.doi.org/10.1107/S2056989016005752 Text en © Tran et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Tran, T. Thanh Van Anh, Le Tuan Nguyen, Hung Huy Truong, Hong Hieu Soldatenkov, Anatoly T. Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title | Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title_full | Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title_fullStr | Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title_full_unstemmed | Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title_short | Crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
title_sort | crystal structure of 26-(4-methylphenyl)-8,11,14,17-tetraoxa-28-azatetracyclo[22.3.1.0(2,7).0(18,23)]hexacosa-2,4,6,18(23),19,21,24(1),25,27-nonaene |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908512/ https://www.ncbi.nlm.nih.gov/pubmed/27308014 http://dx.doi.org/10.1107/S2056989016005752 |
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