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Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene

The title compound, C(30)H(29)NO(4), is a tetra­cyclic system containing a 4-aryl­pyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methyl­phenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benze...

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Autores principales: Tran, T. Thanh Van, Anh, Le Tuan, Nguyen, Hung Huy, Truong, Hong Hieu, Soldatenkov, Anatoly T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908512/
https://www.ncbi.nlm.nih.gov/pubmed/27308014
http://dx.doi.org/10.1107/S2056989016005752
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author Tran, T. Thanh Van
Anh, Le Tuan
Nguyen, Hung Huy
Truong, Hong Hieu
Soldatenkov, Anatoly T.
author_facet Tran, T. Thanh Van
Anh, Le Tuan
Nguyen, Hung Huy
Truong, Hong Hieu
Soldatenkov, Anatoly T.
author_sort Tran, T. Thanh Van
collection PubMed
description The title compound, C(30)H(29)NO(4), is a tetra­cyclic system containing a 4-aryl­pyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methyl­phenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benzene rings. The benzene rings are inclined to one another by 88.32 (6)°. In the crystal, mol­ecules are linked by pairs of C—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via a number of C—H⋯π inter­actions, forming a three-dimensional architecture.
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spelling pubmed-49085122016-06-15 Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene Tran, T. Thanh Van Anh, Le Tuan Nguyen, Hung Huy Truong, Hong Hieu Soldatenkov, Anatoly T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(30)H(29)NO(4), is a tetra­cyclic system containing a 4-aryl­pyridine fragment, two benzene rings and an aza-17-crown-5 ether moiety, in a bowl-like arrangement. The pyridine ring is inclined to the 4-methyl­phenyl ring by 26.64 (6)°, and by 57.43 (6) and 56.81 (6)° to the benzene rings. The benzene rings are inclined to one another by 88.32 (6)°. In the crystal, mol­ecules are linked by pairs of C—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via a number of C—H⋯π inter­actions, forming a three-dimensional architecture. International Union of Crystallography 2016-04-12 /pmc/articles/PMC4908512/ /pubmed/27308014 http://dx.doi.org/10.1107/S2056989016005752 Text en © Tran et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Tran, T. Thanh Van
Anh, Le Tuan
Nguyen, Hung Huy
Truong, Hong Hieu
Soldatenkov, Anatoly T.
Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title_full Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title_fullStr Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title_full_unstemmed Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title_short Crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
title_sort crystal structure of 26-(4-methyl­phen­yl)-8,11,14,17-tetra­oxa-28-aza­tetra­cyclo[22.3.1.0(2,7).0(18,23)]hexa­cosa-2,4,6,18(23),19,21,24(1),25,27-nona­ene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908512/
https://www.ncbi.nlm.nih.gov/pubmed/27308014
http://dx.doi.org/10.1107/S2056989016005752
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