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Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)]
The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adop...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908532/ https://www.ncbi.nlm.nih.gov/pubmed/27308002 http://dx.doi.org/10.1107/S2056989016005284 |
Sumario: | The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO(4) tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O interactions lead to the formation of a three-dimensional network structure. |
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