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Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]

The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis­(3-ammonio­prop­yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adop...

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Autores principales: Vetrivel, S., Vinoth, E., Mullai, R. U., Aruljothi, R., NizamMohideen, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908532/
https://www.ncbi.nlm.nih.gov/pubmed/27308002
http://dx.doi.org/10.1107/S2056989016005284
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author Vetrivel, S.
Vinoth, E.
Mullai, R. U.
Aruljothi, R.
NizamMohideen, M.
author_facet Vetrivel, S.
Vinoth, E.
Mullai, R. U.
Aruljothi, R.
NizamMohideen, M.
author_sort Vetrivel, S.
collection PubMed
description The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis­(3-ammonio­prop­yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO(4) tetra­hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O inter­actions lead to the formation of a three-dimensional network structure.
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spelling pubmed-49085322016-06-15 Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)] Vetrivel, S. Vinoth, E. Mullai, R. U. Aruljothi, R. NizamMohideen, M. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis­(3-ammonio­prop­yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO(4) tetra­hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O inter­actions lead to the formation of a three-dimensional network structure. International Union of Crystallography 2016-04-05 /pmc/articles/PMC4908532/ /pubmed/27308002 http://dx.doi.org/10.1107/S2056989016005284 Text en © Vetrivel et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Vetrivel, S.
Vinoth, E.
Mullai, R. U.
Aruljothi, R.
NizamMohideen, M.
Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title_full Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title_fullStr Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title_full_unstemmed Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title_short Crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(VI)]
title_sort crystal structure of 1,4-bis­(3-ammonio­prop­yl)piperazine-1,4-diium bis­[dichromate(vi)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908532/
https://www.ncbi.nlm.nih.gov/pubmed/27308002
http://dx.doi.org/10.1107/S2056989016005284
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