Cargando…
Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)]
The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adop...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908532/ https://www.ncbi.nlm.nih.gov/pubmed/27308002 http://dx.doi.org/10.1107/S2056989016005284 |
_version_ | 1782437699837231104 |
---|---|
author | Vetrivel, S. Vinoth, E. Mullai, R. U. Aruljothi, R. NizamMohideen, M. |
author_facet | Vetrivel, S. Vinoth, E. Mullai, R. U. Aruljothi, R. NizamMohideen, M. |
author_sort | Vetrivel, S. |
collection | PubMed |
description | The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO(4) tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O interactions lead to the formation of a three-dimensional network structure. |
format | Online Article Text |
id | pubmed-4908532 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49085322016-06-15 Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] Vetrivel, S. Vinoth, E. Mullai, R. U. Aruljothi, R. NizamMohideen, M. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the organic–inorganic title salt, (C(10)H(28)N(4))[Cr(2)O(7)](2), comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO(4) tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O interactions lead to the formation of a three-dimensional network structure. International Union of Crystallography 2016-04-05 /pmc/articles/PMC4908532/ /pubmed/27308002 http://dx.doi.org/10.1107/S2056989016005284 Text en © Vetrivel et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Vetrivel, S. Vinoth, E. Mullai, R. U. Aruljothi, R. NizamMohideen, M. Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title_full | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title_fullStr | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title_full_unstemmed | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title_short | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
title_sort | crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(vi)] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908532/ https://www.ncbi.nlm.nih.gov/pubmed/27308002 http://dx.doi.org/10.1107/S2056989016005284 |
work_keys_str_mv | AT vetrivels crystalstructureof14bis3ammoniopropylpiperazine14diiumbisdichromatevi AT vinothe crystalstructureof14bis3ammoniopropylpiperazine14diiumbisdichromatevi AT mullairu crystalstructureof14bis3ammoniopropylpiperazine14diiumbisdichromatevi AT aruljothir crystalstructureof14bis3ammoniopropylpiperazine14diiumbisdichromatevi AT nizammohideenm crystalstructureof14bis3ammoniopropylpiperazine14diiumbisdichromatevi |