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A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate

In the cation of the title hydrated mol­ecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O,...

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Detalles Bibliográficos
Autores principales: Plater, M. John, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908533/
https://www.ncbi.nlm.nih.gov/pubmed/27307999
http://dx.doi.org/10.1107/S2056989016005107
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author Plater, M. John
Harrison, William T. A.
author_facet Plater, M. John
Harrison, William T. A.
author_sort Plater, M. John
collection PubMed
description In the cation of the title hydrated mol­ecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, generating double layers propagating in (100).
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spelling pubmed-49085332016-06-15 A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate Plater, M. John Harrison, William T. A. Acta Crystallogr E Crystallogr Commun Research Communications In the cation of the title hydrated mol­ecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, generating double layers propagating in (100). International Union of Crystallography 2016-04-05 /pmc/articles/PMC4908533/ /pubmed/27307999 http://dx.doi.org/10.1107/S2056989016005107 Text en © Plater and Harrison 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Plater, M. John
Harrison, William T. A.
A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title_full A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title_fullStr A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title_full_unstemmed A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title_short A purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
title_sort purple odyssey: synthesis and structure of 3-amino-4-hy­droxy-6-oxo­cyclo­hexa-2,4-dien-1-iminium chloride monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908533/
https://www.ncbi.nlm.nih.gov/pubmed/27307999
http://dx.doi.org/10.1107/S2056989016005107
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