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A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate
In the cation of the title hydrated molecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908533/ https://www.ncbi.nlm.nih.gov/pubmed/27307999 http://dx.doi.org/10.1107/S2056989016005107 |
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author | Plater, M. John Harrison, William T. A. |
author_facet | Plater, M. John Harrison, William T. A. |
author_sort | Plater, M. John |
collection | PubMed |
description | In the cation of the title hydrated molecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, generating double layers propagating in (100). |
format | Online Article Text |
id | pubmed-4908533 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49085332016-06-15 A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate Plater, M. John Harrison, William T. A. Acta Crystallogr E Crystallogr Commun Research Communications In the cation of the title hydrated molecular salt, C(6)H(7)N(2)O(2) (+)·Cl(−)·H(2)O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H⋯Cl, N—H⋯O, O—H⋯Cl and O—H⋯O hydrogen bonds, generating double layers propagating in (100). International Union of Crystallography 2016-04-05 /pmc/articles/PMC4908533/ /pubmed/27307999 http://dx.doi.org/10.1107/S2056989016005107 Text en © Plater and Harrison 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Plater, M. John Harrison, William T. A. A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title | A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title_full | A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title_fullStr | A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title_full_unstemmed | A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title_short | A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
title_sort | purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908533/ https://www.ncbi.nlm.nih.gov/pubmed/27307999 http://dx.doi.org/10.1107/S2056989016005107 |
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