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(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
In the title compound, C(23)H(14)ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908534/ https://www.ncbi.nlm.nih.gov/pubmed/27308010 http://dx.doi.org/10.1107/S2056989016005028 |
| _version_ | 1782437700302798848 |
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| author | Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Khalib, Nuridayanti Che Razak, Ibrahim Abdul |
| author_facet | Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Khalib, Nuridayanti Che Razak, Ibrahim Abdul |
| author_sort | Abdullah, Amzar Ahlami |
| collection | PubMed |
| description | In the title compound, C(23)H(14)ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π interactions. Hirshfeld surface analysis was used to confirm the existence of intermolecular interactions. |
| format | Online Article Text |
| id | pubmed-4908534 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-49085342016-06-15 (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Khalib, Nuridayanti Che Razak, Ibrahim Abdul Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(23)H(14)ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π interactions. Hirshfeld surface analysis was used to confirm the existence of intermolecular interactions. International Union of Crystallography 2016-04-08 /pmc/articles/PMC4908534/ /pubmed/27308010 http://dx.doi.org/10.1107/S2056989016005028 Text en © Abdullah et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Khalib, Nuridayanti Che Razak, Ibrahim Abdul (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title | (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title_full | (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title_fullStr | (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title_short | (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis |
| title_sort | (e)-1-(anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and hirshfeld surface analysis |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908534/ https://www.ncbi.nlm.nih.gov/pubmed/27308010 http://dx.doi.org/10.1107/S2056989016005028 |
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