Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate

In the title compound, C(23)H(18)N(3)O(3) (+)·CF(3)SO(3) (−), the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of...

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Autores principales: Nicolas-Gomez, Mariana, Bazany-Rodríguez, Iván J., Plata-Vargas, Eduardo, Hernández-Ortega, Simón, Dorazco-González, Alejandro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908536/
https://www.ncbi.nlm.nih.gov/pubmed/27308033
http://dx.doi.org/10.1107/S2056989016006423
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author Nicolas-Gomez, Mariana
Bazany-Rodríguez, Iván J.
Plata-Vargas, Eduardo
Hernández-Ortega, Simón
Dorazco-González, Alejandro
author_facet Nicolas-Gomez, Mariana
Bazany-Rodríguez, Iván J.
Plata-Vargas, Eduardo
Hernández-Ortega, Simón
Dorazco-González, Alejandro
author_sort Nicolas-Gomez, Mariana
collection PubMed
description In the title compound, C(23)H(18)N(3)O(3) (+)·CF(3)SO(3) (−), the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90 (2) and 31.66 (2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99 (4) and 8.54 (4)°. The tri­fluoro­methane­sulfonate anions are linked to the organic cations via N—H⋯O hydrogen-bonding inter­actions involving the NH amide groups. In the crystal, the organic cations are linked by weak C—H⋯O(nitro group) inter­actions into supramol­ecular chains propagating along the b-axis direction.
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spelling pubmed-49085362016-06-15 Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate Nicolas-Gomez, Mariana Bazany-Rodríguez, Iván J. Plata-Vargas, Eduardo Hernández-Ortega, Simón Dorazco-González, Alejandro Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(23)H(18)N(3)O(3) (+)·CF(3)SO(3) (−), the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90 (2) and 31.66 (2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99 (4) and 8.54 (4)°. The tri­fluoro­methane­sulfonate anions are linked to the organic cations via N—H⋯O hydrogen-bonding inter­actions involving the NH amide groups. In the crystal, the organic cations are linked by weak C—H⋯O(nitro group) inter­actions into supramol­ecular chains propagating along the b-axis direction. International Union of Crystallography 2016-04-29 /pmc/articles/PMC4908536/ /pubmed/27308033 http://dx.doi.org/10.1107/S2056989016006423 Text en © Nicolas-Gomez et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Nicolas-Gomez, Mariana
Bazany-Rodríguez, Iván J.
Plata-Vargas, Eduardo
Hernández-Ortega, Simón
Dorazco-González, Alejandro
Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title_full Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title_fullStr Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title_full_unstemmed Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title_short Crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
title_sort crystal structure of 3-benzamido-1-(4-nitro­benz­yl)quinolinium tri­fluoro­methane­sulfonate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908536/
https://www.ncbi.nlm.nih.gov/pubmed/27308033
http://dx.doi.org/10.1107/S2056989016006423
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