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Crystal structure of bis(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis[n-butyltrichloridostannate(IV)]
The Sn(IV) atom in the centrosymmetric anion of the title salt, (C(4)H(7)N(2))(2)[Sn(2)(C(4)H(9))(2)(C(2)O(4))Cl(6)], is coordinated in a distorted octahedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908556/ https://www.ncbi.nlm.nih.gov/pubmed/27308059 http://dx.doi.org/10.1107/S2056989016008434 |
Sumario: | The Sn(IV) atom in the centrosymmetric anion of the title salt, (C(4)H(7)N(2))(2)[Sn(2)(C(4)H(9))(2)(C(2)O(4))Cl(6)], is coordinated in a distorted octahedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N—H⋯O and N—H⋯Cl hydrogen bonds involving the 2-methylimidazolium cation and neighbouring anions result in the formation of chains extending parallel to [001]. |
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