Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]

The Sn(IV) atom in the centrosymmetric anion of the title salt, (C(4)H(7)N(2))(2)[Sn(2)(C(4)H(9))(2)(C(2)O(4))Cl(6)], is coordinated in a distorted octa­hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of...

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Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908556/
https://www.ncbi.nlm.nih.gov/pubmed/27308059
http://dx.doi.org/10.1107/S2056989016008434
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author Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_sort Diop, Mouhamadou Birame
collection PubMed
description The Sn(IV) atom in the centrosymmetric anion of the title salt, (C(4)H(7)N(2))(2)[Sn(2)(C(4)H(9))(2)(C(2)O(4))Cl(6)], is coordinated in a distorted octa­hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N—H⋯O and N—H⋯Cl hydrogen bonds involving the 2-methyl­imidazolium cation and neighbouring anions result in the formation of chains extending parallel to [001].
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spelling pubmed-49085562016-06-15 Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)] Diop, Mouhamadou Birame Diop, Libasse Oliver, Allen G. Acta Crystallogr E Crystallogr Commun Research Communications The Sn(IV) atom in the centrosymmetric anion of the title salt, (C(4)H(7)N(2))(2)[Sn(2)(C(4)H(9))(2)(C(2)O(4))Cl(6)], is coordinated in a distorted octa­hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N—H⋯O and N—H⋯Cl hydrogen bonds involving the 2-methyl­imidazolium cation and neighbouring anions result in the formation of chains extending parallel to [001]. International Union of Crystallography 2016-05-27 /pmc/articles/PMC4908556/ /pubmed/27308059 http://dx.doi.org/10.1107/S2056989016008434 Text en © Diop et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title_full Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title_fullStr Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title_full_unstemmed Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title_short Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(IV)]
title_sort crystal structure of bis­(2-methyl-1h-imidazol-3-ium) μ-oxalato-bis­[n-butyl­tri­chlorido­stannate(iv)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908556/
https://www.ncbi.nlm.nih.gov/pubmed/27308059
http://dx.doi.org/10.1107/S2056989016008434
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