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m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis

The crystal structure of the title salt {systematic name: [1,3-phenyl­enebis(methyl­ene)]bis­(aza­nium) sulfate}, C(8)H(14)N(2) (2+)·SO(4) (2−), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N—H⋯O a...

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Detalles Bibliográficos
Autores principales: Guesmi, Afef, Gatfaoui, Sofian, Roisnel, Thierry, Marouani, Houda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908557/
https://www.ncbi.nlm.nih.gov/pubmed/27308040
http://dx.doi.org/10.1107/S2056989016006940
Descripción
Sumario:The crystal structure of the title salt {systematic name: [1,3-phenyl­enebis(methyl­ene)]bis­(aza­nium) sulfate}, C(8)H(14)N(2) (2+)·SO(4) (2−), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N—H⋯O and asymmetric bifurcated N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network. A weak C—H⋯O inter­action also occurs. The Hirshfeld surface analysis and the two-dimensional fingerprint maps indicate that the packing is dominated by H⋯O/O⋯H and H⋯H contacts.