m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis

The crystal structure of the title salt {systematic name: [1,3-phenyl­enebis(methyl­ene)]bis­(aza­nium) sulfate}, C(8)H(14)N(2) (2+)·SO(4) (2−), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N—H⋯O a...

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Autores principales: Guesmi, Afef, Gatfaoui, Sofian, Roisnel, Thierry, Marouani, Houda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908557/
https://www.ncbi.nlm.nih.gov/pubmed/27308040
http://dx.doi.org/10.1107/S2056989016006940
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author Guesmi, Afef
Gatfaoui, Sofian
Roisnel, Thierry
Marouani, Houda
author_facet Guesmi, Afef
Gatfaoui, Sofian
Roisnel, Thierry
Marouani, Houda
author_sort Guesmi, Afef
collection PubMed
description The crystal structure of the title salt {systematic name: [1,3-phenyl­enebis(methyl­ene)]bis­(aza­nium) sulfate}, C(8)H(14)N(2) (2+)·SO(4) (2−), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N—H⋯O and asymmetric bifurcated N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network. A weak C—H⋯O inter­action also occurs. The Hirshfeld surface analysis and the two-dimensional fingerprint maps indicate that the packing is dominated by H⋯O/O⋯H and H⋯H contacts.
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spelling pubmed-49085572016-06-15 m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis Guesmi, Afef Gatfaoui, Sofian Roisnel, Thierry Marouani, Houda Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title salt {systematic name: [1,3-phenyl­enebis(methyl­ene)]bis­(aza­nium) sulfate}, C(8)H(14)N(2) (2+)·SO(4) (2−), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N—H⋯O and asymmetric bifurcated N—H⋯(O,O) hydrogen bonds, generating a three-dimensional network. A weak C—H⋯O inter­action also occurs. The Hirshfeld surface analysis and the two-dimensional fingerprint maps indicate that the packing is dominated by H⋯O/O⋯H and H⋯H contacts. International Union of Crystallography 2016-05-04 /pmc/articles/PMC4908557/ /pubmed/27308040 http://dx.doi.org/10.1107/S2056989016006940 Text en © Guesmi et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Guesmi, Afef
Gatfaoui, Sofian
Roisnel, Thierry
Marouani, Houda
m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title_full m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title_fullStr m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title_full_unstemmed m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title_short m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis
title_sort m-xylylenediaminium sulfate: crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908557/
https://www.ncbi.nlm.nih.gov/pubmed/27308040
http://dx.doi.org/10.1107/S2056989016006940
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