Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)

The synthesis, structure, and magnetic properties of lithium dibarium calcium oxide fluoride di­sulfide are reported. LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2) crystallizes in the tetra­gonal space group P4/nmm. The structure exhibits disorder of the Ca(2+) and Bi(3+) cations, and the...

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Autores principales: Huang, Rongtie, Zhang, Hui, Wang, Dong, Cai, Chuanbing, Huang, Fuqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908565/
https://www.ncbi.nlm.nih.gov/pubmed/27308056
http://dx.doi.org/10.1107/S2056989016008082
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author Huang, Rongtie
Zhang, Hui
Wang, Dong
Cai, Chuanbing
Huang, Fuqiang
author_facet Huang, Rongtie
Zhang, Hui
Wang, Dong
Cai, Chuanbing
Huang, Fuqiang
author_sort Huang, Rongtie
collection PubMed
description The synthesis, structure, and magnetic properties of lithium dibarium calcium oxide fluoride di­sulfide are reported. LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2) crystallizes in the tetra­gonal space group P4/nmm. The structure exhibits disorder of the Ca(2+) and Bi(3+) cations, and the O(2−) and F(−) anions. The structure is composed of a stacking of [(O,F)(2)La(2)] layers and double [(Bi,Ca)S(2)] layers. Magnetic property measurements indicate a very small magnetization at 300 K and the existence of weak ferromagnetism at 2 K.
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spelling pubmed-49085652016-06-15 Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2) Huang, Rongtie Zhang, Hui Wang, Dong Cai, Chuanbing Huang, Fuqiang Acta Crystallogr E Crystallogr Commun Research Communications The synthesis, structure, and magnetic properties of lithium dibarium calcium oxide fluoride di­sulfide are reported. LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2) crystallizes in the tetra­gonal space group P4/nmm. The structure exhibits disorder of the Ca(2+) and Bi(3+) cations, and the O(2−) and F(−) anions. The structure is composed of a stacking of [(O,F)(2)La(2)] layers and double [(Bi,Ca)S(2)] layers. Magnetic property measurements indicate a very small magnetization at 300 K and the existence of weak ferromagnetism at 2 K. International Union of Crystallography 2016-05-24 /pmc/articles/PMC4908565/ /pubmed/27308056 http://dx.doi.org/10.1107/S2056989016008082 Text en © Huang et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Huang, Rongtie
Zhang, Hui
Wang, Dong
Cai, Chuanbing
Huang, Fuqiang
Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title_full Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title_fullStr Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title_full_unstemmed Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title_short Crystal structure and magnetic properties of LaCa(0.143 (4))O(0.857 (4))F(0.143 (4))Bi(0.857 (4))S(2)
title_sort crystal structure and magnetic properties of laca(0.143 (4))o(0.857 (4))f(0.143 (4))bi(0.857 (4))s(2)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908565/
https://www.ncbi.nlm.nih.gov/pubmed/27308056
http://dx.doi.org/10.1107/S2056989016008082
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