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Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate
The title compound, C(12)H(7)Cl(3)O(3)S, was synthesized via a nucleophilic substitution reaction between phenol and 2,4,5-trichlorobenzenesulfonyl chloride. The two aryl rings are oriented gauche to one another around the sulfonate S—O bond, with a C—S—O—C torsion angle of −70.68 (16)°, and the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908567/ https://www.ncbi.nlm.nih.gov/pubmed/27308043 http://dx.doi.org/10.1107/S2056989016007325 |
| _version_ | 1782437707805360128 |
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| author | Riley, Sean Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. |
| author_facet | Riley, Sean Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. |
| author_sort | Riley, Sean |
| collection | PubMed |
| description | The title compound, C(12)H(7)Cl(3)O(3)S, was synthesized via a nucleophilic substitution reaction between phenol and 2,4,5-trichlorobenzenesulfonyl chloride. The two aryl rings are oriented gauche to one another around the sulfonate S—O bond, with a C—S—O—C torsion angle of −70.68 (16)°, and the two rings are inclined to one another by 72.40 (7)°. In the crystal, molecules are linked via various C—Cl⋯π interactions, forming ribbons propagating along [100]. Neighboring ribbons are linked by a weak C—Cl⋯π interaction, forming layers parallel to (010). |
| format | Online Article Text |
| id | pubmed-4908567 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-49085672016-06-15 Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate Riley, Sean Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(12)H(7)Cl(3)O(3)S, was synthesized via a nucleophilic substitution reaction between phenol and 2,4,5-trichlorobenzenesulfonyl chloride. The two aryl rings are oriented gauche to one another around the sulfonate S—O bond, with a C—S—O—C torsion angle of −70.68 (16)°, and the two rings are inclined to one another by 72.40 (7)°. In the crystal, molecules are linked via various C—Cl⋯π interactions, forming ribbons propagating along [100]. Neighboring ribbons are linked by a weak C—Cl⋯π interaction, forming layers parallel to (010). International Union of Crystallography 2016-05-06 /pmc/articles/PMC4908567/ /pubmed/27308043 http://dx.doi.org/10.1107/S2056989016007325 Text en © Riley et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Riley, Sean Staples, Richard J. Biros, Shannon M. Ngassa, Felix N. Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title | Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title_full | Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title_fullStr | Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title_full_unstemmed | Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title_short | Crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| title_sort | crystal structure of phenyl 2,4,5-trichlorobenzenesulfonate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908567/ https://www.ncbi.nlm.nih.gov/pubmed/27308043 http://dx.doi.org/10.1107/S2056989016007325 |
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