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Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2) N,O}bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane monosolvate
In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenylimino)methyl]phenolate anion, giving rise to a distorted octahedral environment. The C,N-bidentate ligands,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908569/ https://www.ncbi.nlm.nih.gov/pubmed/27308054 http://dx.doi.org/10.1107/S2056989016008100 |
Sumario: | In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenylimino)methyl]phenolate anion, giving rise to a distorted octahedral environment. The C,N-bidentate ligands, in which the C and N atoms are statistically disordered over two sites and therefore both pairs of C and N atoms are trans and cis relative to each other, are almost perpendicular to each other [the dihedral angle between the least-square planes is 87.00 (4)°]. An intramolecular C—H⋯O hydrogen bond, as well as intermolecular C—H⋯π interactions and π–π interactions, contribute to the stabilization of the molecular and crystal structure. |
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