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Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate

In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenyl­imino)­meth­yl]phenolate anion, giving rise to a distorted octa­hedral environment. The C,N-bidentate ligands,...

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Autores principales: Goo, Moo-Sung, Park, Ki-Min, Kim, Hee-Joon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908569/
https://www.ncbi.nlm.nih.gov/pubmed/27308054
http://dx.doi.org/10.1107/S2056989016008100
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author Goo, Moo-Sung
Park, Ki-Min
Kim, Hee-Joon
author_facet Goo, Moo-Sung
Park, Ki-Min
Kim, Hee-Joon
author_sort Goo, Moo-Sung
collection PubMed
description In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenyl­imino)­meth­yl]phenolate anion, giving rise to a distorted octa­hedral environment. The C,N-bidentate ligands, in which the C and N atoms are statistically disordered over two sites and therefore both pairs of C and N atoms are trans and cis relative to each other, are almost perpendicular to each other [the dihedral angle between the least-square planes is 87.00 (4)°]. An intra­molecular C—H⋯O hydrogen bond, as well as inter­molecular C—H⋯π inter­actions and π–π inter­actions, contribute to the stabilization of the mol­ecular and crystal structure.
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spelling pubmed-49085692016-06-15 Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate Goo, Moo-Sung Park, Ki-Min Kim, Hee-Joon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenyl­imino)­meth­yl]phenolate anion, giving rise to a distorted octa­hedral environment. The C,N-bidentate ligands, in which the C and N atoms are statistically disordered over two sites and therefore both pairs of C and N atoms are trans and cis relative to each other, are almost perpendicular to each other [the dihedral angle between the least-square planes is 87.00 (4)°]. An intra­molecular C—H⋯O hydrogen bond, as well as inter­molecular C—H⋯π inter­actions and π–π inter­actions, contribute to the stabilization of the mol­ecular and crystal structure. International Union of Crystallography 2016-05-20 /pmc/articles/PMC4908569/ /pubmed/27308054 http://dx.doi.org/10.1107/S2056989016008100 Text en © Goo et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Goo, Moo-Sung
Park, Ki-Min
Kim, Hee-Joon
Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title_full Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title_fullStr Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title_full_unstemmed Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title_short Crystal structure of {(E)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) N,O}bis­[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di­chloro­methane monosolvate
title_sort crystal structure of {(e)-2-[(phenyl­imino)­meth­yl]phenolato-κ(2) n,o}bis­[2-(pyridin-2-yl)phenyl-κ(2) c (1),n]iridium(iii) di­chloro­methane monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908569/
https://www.ncbi.nlm.nih.gov/pubmed/27308054
http://dx.doi.org/10.1107/S2056989016008100
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