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Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2) N,O}bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane monosolvate
In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenylimino)methyl]phenolate anion, giving rise to a distorted octahedral environment. The C,N-bidentate ligands,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908569/ https://www.ncbi.nlm.nih.gov/pubmed/27308054 http://dx.doi.org/10.1107/S2056989016008100 |
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author | Goo, Moo-Sung Park, Ki-Min Kim, Hee-Joon |
author_facet | Goo, Moo-Sung Park, Ki-Min Kim, Hee-Joon |
author_sort | Goo, Moo-Sung |
collection | PubMed |
description | In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenylimino)methyl]phenolate anion, giving rise to a distorted octahedral environment. The C,N-bidentate ligands, in which the C and N atoms are statistically disordered over two sites and therefore both pairs of C and N atoms are trans and cis relative to each other, are almost perpendicular to each other [the dihedral angle between the least-square planes is 87.00 (4)°]. An intramolecular C—H⋯O hydrogen bond, as well as intermolecular C—H⋯π interactions and π–π interactions, contribute to the stabilization of the molecular and crystal structure. |
format | Online Article Text |
id | pubmed-4908569 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49085692016-06-15 Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2) N,O}bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane monosolvate Goo, Moo-Sung Park, Ki-Min Kim, Hee-Joon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Ir(C(11)H(8)N)(2)(C(13)H(10)NO)]·CH(2)Cl(2), the Ir(III) ion is six-coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one N,O-bidentate 2-[(phenylimino)methyl]phenolate anion, giving rise to a distorted octahedral environment. The C,N-bidentate ligands, in which the C and N atoms are statistically disordered over two sites and therefore both pairs of C and N atoms are trans and cis relative to each other, are almost perpendicular to each other [the dihedral angle between the least-square planes is 87.00 (4)°]. An intramolecular C—H⋯O hydrogen bond, as well as intermolecular C—H⋯π interactions and π–π interactions, contribute to the stabilization of the molecular and crystal structure. International Union of Crystallography 2016-05-20 /pmc/articles/PMC4908569/ /pubmed/27308054 http://dx.doi.org/10.1107/S2056989016008100 Text en © Goo et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Goo, Moo-Sung Park, Ki-Min Kim, Hee-Joon Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2) N,O}bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) dichloromethane monosolvate |
title | Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2)
N,O}bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane monosolvate |
title_full | Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2)
N,O}bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane monosolvate |
title_fullStr | Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2)
N,O}bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane monosolvate |
title_full_unstemmed | Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2)
N,O}bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane monosolvate |
title_short | Crystal structure of {(E)-2-[(phenylimino)methyl]phenolato-κ(2)
N,O}bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) dichloromethane monosolvate |
title_sort | crystal structure of {(e)-2-[(phenylimino)methyl]phenolato-κ(2)
n,o}bis[2-(pyridin-2-yl)phenyl-κ(2)
c
(1),n]iridium(iii) dichloromethane monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908569/ https://www.ncbi.nlm.nih.gov/pubmed/27308054 http://dx.doi.org/10.1107/S2056989016008100 |
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