Synthesis and crystal structure of NaMgFe(MoO(4))(3)

The iron molybdate NaMgFe(MoO(4))(3) {sodium magnesium iron(III) tris­[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe(2)(MoO(4))(3) and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe](2)O(10) units of edge-sha...

Descripción completa

Detalles Bibliográficos
Autores principales: Mhiri, Manel, Badri, Abdessalem, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908571/
https://www.ncbi.nlm.nih.gov/pubmed/27308061
http://dx.doi.org/10.1107/S205698901600829X
Descripción
Sumario:The iron molybdate NaMgFe(MoO(4))(3) {sodium magnesium iron(III) tris­[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe(2)(MoO(4))(3) and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe](2)O(10) units of edge-sharing [Mg,Fe]O(6) octa­hedra which are linked to each other through the common corners of [MoO(4)] tetra­hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direction in which the Na(+) cations are located.

Ejemplares similares