Synthesis and crystal structure of NaMgFe(MoO(4))(3)

The iron molybdate NaMgFe(MoO(4))(3) {sodium magnesium iron(III) tris­[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe(2)(MoO(4))(3) and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe](2)O(10) units of edge-sha...

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Autores principales: Mhiri, Manel, Badri, Abdessalem, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908571/
https://www.ncbi.nlm.nih.gov/pubmed/27308061
http://dx.doi.org/10.1107/S205698901600829X
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author Mhiri, Manel
Badri, Abdessalem
Ben Amara, Mongi
author_facet Mhiri, Manel
Badri, Abdessalem
Ben Amara, Mongi
author_sort Mhiri, Manel
collection PubMed
description The iron molybdate NaMgFe(MoO(4))(3) {sodium magnesium iron(III) tris­[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe(2)(MoO(4))(3) and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe](2)O(10) units of edge-sharing [Mg,Fe]O(6) octa­hedra which are linked to each other through the common corners of [MoO(4)] tetra­hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direction in which the Na(+) cations are located.
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spelling pubmed-49085712016-06-15 Synthesis and crystal structure of NaMgFe(MoO(4))(3) Mhiri, Manel Badri, Abdessalem Ben Amara, Mongi Acta Crystallogr E Crystallogr Commun Research Communications The iron molybdate NaMgFe(MoO(4))(3) {sodium magnesium iron(III) tris­[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe(2)(MoO(4))(3) and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe](2)O(10) units of edge-sharing [Mg,Fe]O(6) octa­hedra which are linked to each other through the common corners of [MoO(4)] tetra­hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direction in which the Na(+) cations are located. International Union of Crystallography 2016-05-27 /pmc/articles/PMC4908571/ /pubmed/27308061 http://dx.doi.org/10.1107/S205698901600829X Text en © Mhiri et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mhiri, Manel
Badri, Abdessalem
Ben Amara, Mongi
Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title_full Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title_fullStr Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title_full_unstemmed Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title_short Synthesis and crystal structure of NaMgFe(MoO(4))(3)
title_sort synthesis and crystal structure of namgfe(moo(4))(3)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908571/
https://www.ncbi.nlm.nih.gov/pubmed/27308061
http://dx.doi.org/10.1107/S205698901600829X
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AT badriabdessalem synthesisandcrystalstructureofnamgfemoo43
AT benamaramongi synthesisandcrystalstructureofnamgfemoo43

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