Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)

Reaction of m-amino­benzoic acid (MABA), di­ethano­lamine (DEA) and MnCl(2)·4H(2)O led to the formation of the title salt, [Mn(C(4)H(11)NO(2))(2)](C(7)H(6)NO(2))(2). In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol­...

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Autores principales: Ibragimov, Aziz B., Zakirov, Bakhtiyar S., Ashurov, Jamshid M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910313/
https://www.ncbi.nlm.nih.gov/pubmed/27375875
http://dx.doi.org/10.1107/S2056989016004072
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author Ibragimov, Aziz B.
Zakirov, Bakhtiyar S.
Ashurov, Jamshid M.
author_facet Ibragimov, Aziz B.
Zakirov, Bakhtiyar S.
Ashurov, Jamshid M.
author_sort Ibragimov, Aziz B.
collection PubMed
description Reaction of m-amino­benzoic acid (MABA), di­ethano­lamine (DEA) and MnCl(2)·4H(2)O led to the formation of the title salt, [Mn(C(4)H(11)NO(2))(2)](C(7)H(6)NO(2))(2). In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol­ecules, leading to the formation of a slightly distorted MnN(2)O(4) octa­hedron. The MABA(−) counter-anions are connected to the complex ion by a pair of rather strong O—H⋯O hydrogen bonds, yielding a 1:2 supra­molecular aggregate. Much weaker N—H⋯O hydrogen bonds connect neighbouring aggregates into a three-dimensional network structure.
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spelling pubmed-49103132016-07-01 Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate) Ibragimov, Aziz B. Zakirov, Bakhtiyar S. Ashurov, Jamshid M. Acta Crystallogr E Crystallogr Commun Research Communications Reaction of m-amino­benzoic acid (MABA), di­ethano­lamine (DEA) and MnCl(2)·4H(2)O led to the formation of the title salt, [Mn(C(4)H(11)NO(2))(2)](C(7)H(6)NO(2))(2). In the complex cation, the Mn(2+) ion is located on an inversion centre and is coordinated by two symmetry-related tridentate DEA mol­ecules, leading to the formation of a slightly distorted MnN(2)O(4) octa­hedron. The MABA(−) counter-anions are connected to the complex ion by a pair of rather strong O—H⋯O hydrogen bonds, yielding a 1:2 supra­molecular aggregate. Much weaker N—H⋯O hydrogen bonds connect neighbouring aggregates into a three-dimensional network structure. International Union of Crystallography 2016-03-15 /pmc/articles/PMC4910313/ /pubmed/27375875 http://dx.doi.org/10.1107/S2056989016004072 Text en © Ibragimov et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ibragimov, Aziz B.
Zakirov, Bakhtiyar S.
Ashurov, Jamshid M.
Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title_full Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title_fullStr Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title_full_unstemmed Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title_short Crystal structure of trans-bis­(di­ethano­lamine-κ(3) O,N,O′)manganese(II) bis­(3-amino­benzoate)
title_sort crystal structure of trans-bis­(di­ethano­lamine-κ(3) o,n,o′)manganese(ii) bis­(3-amino­benzoate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910313/
https://www.ncbi.nlm.nih.gov/pubmed/27375875
http://dx.doi.org/10.1107/S2056989016004072
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