Cargando…
Crystal structure of bis{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate
The structure of the dinuclear title complex, [Cu(2)(C(10)H(8)N(7))(2)(NO(3))(2)(H(2)O)(2)]·2H(2)O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The Cu(II) ions in the dimer display a distorted octahedral coordination geometry and are bridged by two tri...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910315/ https://www.ncbi.nlm.nih.gov/pubmed/27375870 http://dx.doi.org/10.1107/S2056989016003479 |
Sumario: | The structure of the dinuclear title complex, [Cu(2)(C(10)H(8)N(7))(2)(NO(3))(2)(H(2)O)(2)]·2H(2)O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The Cu(II) ions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu(2)N(4) core (r.m.s. deviation = 0.049 Å). In the crystal, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network. |
---|