Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate

The structure of the dinuclear title complex, [Cu(2)(C(10)H(8)N(7))(2)(NO(3))(2)(H(2)O)(2)]·2H(2)O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The Cu(II) ions in the dimer display a distorted octa­hedral coordination geometry and are bridged by two tri...

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Autor principal: Doroschuk, Roman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910315/
https://www.ncbi.nlm.nih.gov/pubmed/27375870
http://dx.doi.org/10.1107/S2056989016003479
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author Doroschuk, Roman
author_facet Doroschuk, Roman
author_sort Doroschuk, Roman
collection PubMed
description The structure of the dinuclear title complex, [Cu(2)(C(10)H(8)N(7))(2)(NO(3))(2)(H(2)O)(2)]·2H(2)O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The Cu(II) ions in the dimer display a distorted octa­hedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu(2)N(4) core (r.m.s. deviation = 0.049 Å). In the crystal, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and π–π inter­actions link the mol­ecules into a three-dimensional network.
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spelling pubmed-49103152016-07-01 Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate Doroschuk, Roman Acta Crystallogr E Crystallogr Commun Research Communications The structure of the dinuclear title complex, [Cu(2)(C(10)H(8)N(7))(2)(NO(3))(2)(H(2)O)(2)]·2H(2)O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The Cu(II) ions in the dimer display a distorted octa­hedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu(2)N(4) core (r.m.s. deviation = 0.049 Å). In the crystal, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and π–π inter­actions link the mol­ecules into a three-dimensional network. International Union of Crystallography 2016-03-11 /pmc/articles/PMC4910315/ /pubmed/27375870 http://dx.doi.org/10.1107/S2056989016003479 Text en © Roman Doroschuk 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Doroschuk, Roman
Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title_full Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title_fullStr Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title_full_unstemmed Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title_short Crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(II)] dihydrate
title_sort crystal structure of bis­{μ(2)-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)meth­yl]-1,2,4-triazolato}bis­[aqua­nitrato­copper(ii)] dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910315/
https://www.ncbi.nlm.nih.gov/pubmed/27375870
http://dx.doi.org/10.1107/S2056989016003479
work_keys_str_mv AT doroschukroman crystalstructureofbism23pyridin2yl5124triazol1ylmethyl124triazolatobisaquanitratocopperiidihydrate

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