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Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate
In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediylidene)bis(ethan-1-yl-1-ylidene)]bis(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-dihydroxyacetophenone azine molecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910326/ https://www.ncbi.nlm.nih.gov/pubmed/27375866 http://dx.doi.org/10.1107/S2056989016003686 |
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author | Li, Wen-Juan Han, Hong-Fei |
author_facet | Li, Wen-Juan Han, Hong-Fei |
author_sort | Li, Wen-Juan |
collection | PubMed |
description | In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediylidene)bis(ethan-1-yl-1-ylidene)]bis(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-dihydroxyacetophenone azine molecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre. All the non-H atoms of the azine molecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intramolecular O—H⋯N hydrogen bond occurs between the azine N atom and the hydroxy group. In the crystal, azine and dimethylformamide solvent molecules are linked by O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-4910326 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49103262016-07-01 Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate Li, Wen-Juan Han, Hong-Fei Acta Crystallogr E Crystallogr Commun Research Communications In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediylidene)bis(ethan-1-yl-1-ylidene)]bis(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-dihydroxyacetophenone azine molecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre. All the non-H atoms of the azine molecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intramolecular O—H⋯N hydrogen bond occurs between the azine N atom and the hydroxy group. In the crystal, azine and dimethylformamide solvent molecules are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2016-03-08 /pmc/articles/PMC4910326/ /pubmed/27375866 http://dx.doi.org/10.1107/S2056989016003686 Text en © Li and Han 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Li, Wen-Juan Han, Hong-Fei Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title | Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title_full | Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title_fullStr | Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title_full_unstemmed | Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title_short | Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
title_sort | crystal structure of (e,e)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910326/ https://www.ncbi.nlm.nih.gov/pubmed/27375866 http://dx.doi.org/10.1107/S2056989016003686 |
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