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Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate

In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediyl­idene)bis­(ethan-1-yl-1-yl­idene)]bis­(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-di­hydroxy­aceto­phenone azine mol­ecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre...

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Autores principales: Li, Wen-Juan, Han, Hong-Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910326/
https://www.ncbi.nlm.nih.gov/pubmed/27375866
http://dx.doi.org/10.1107/S2056989016003686
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author Li, Wen-Juan
Han, Hong-Fei
author_facet Li, Wen-Juan
Han, Hong-Fei
author_sort Li, Wen-Juan
collection PubMed
description In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediyl­idene)bis­(ethan-1-yl-1-yl­idene)]bis­(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-di­hydroxy­aceto­phenone azine mol­ecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre. All the non-H atoms of the azine mol­ecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intra­molecular O—H⋯N hydrogen bond occurs between the azine N atom and the hy­droxy group. In the crystal, azine and di­methyl­formamide solvent mol­ecules are linked by O—H⋯O hydrogen bonds.
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spelling pubmed-49103262016-07-01 Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate Li, Wen-Juan Han, Hong-Fei Acta Crystallogr E Crystallogr Commun Research Communications In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediyl­idene)bis­(ethan-1-yl-1-yl­idene)]bis­(benzene-1,3-diol)}, C(16)H(16)N(2)O(4)·2C(3)H(7)NO, the (E,E)-2′,4′-di­hydroxy­aceto­phenone azine mol­ecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre. All the non-H atoms of the azine mol­ecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intra­molecular O—H⋯N hydrogen bond occurs between the azine N atom and the hy­droxy group. In the crystal, azine and di­methyl­formamide solvent mol­ecules are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2016-03-08 /pmc/articles/PMC4910326/ /pubmed/27375866 http://dx.doi.org/10.1107/S2056989016003686 Text en © Li and Han 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Li, Wen-Juan
Han, Hong-Fei
Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title_full Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title_fullStr Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title_full_unstemmed Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title_short Crystal structure of (E,E)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
title_sort crystal structure of (e,e)-2′,4′-di­hydroxy­aceto­phenone azine di­methyl­formamide disolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910326/
https://www.ncbi.nlm.nih.gov/pubmed/27375866
http://dx.doi.org/10.1107/S2056989016003686
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