Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)

In the title salt, [Eu(C(3)H(7)NO)(8)][PMo(12)O(40)], the asymmetric unit comprises one α-Keggin-type [PMo(12)O(40)](3−) polyoxidometalate anion and one distorted dodeca­hedral [Eu(C(3)H(7)NO)(8)](3+) complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexa­gonally...

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Autores principales: Ghandour, Yassine, Hammami, Imen, Najmudin, Shabir, Bonifácio, Cecilia, Belkhiria, Mohamed Salah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910337/
https://www.ncbi.nlm.nih.gov/pubmed/27375861
http://dx.doi.org/10.1107/S2056989016003546
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author Ghandour, Yassine
Hammami, Imen
Najmudin, Shabir
Bonifácio, Cecilia
Belkhiria, Mohamed Salah
author_facet Ghandour, Yassine
Hammami, Imen
Najmudin, Shabir
Bonifácio, Cecilia
Belkhiria, Mohamed Salah
author_sort Ghandour, Yassine
collection PubMed
description In the title salt, [Eu(C(3)H(7)NO)(8)][PMo(12)O(40)], the asymmetric unit comprises one α-Keggin-type [PMo(12)O(40)](3−) polyoxidometalate anion and one distorted dodeca­hedral [Eu(C(3)H(7)NO)(8)](3+) complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexa­gonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H⋯O hydrogen-bonding inter­actions, leading to the formation of a three-dimensional network structure.
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spelling pubmed-49103372016-07-01 Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI) Ghandour, Yassine Hammami, Imen Najmudin, Shabir Bonifácio, Cecilia Belkhiria, Mohamed Salah Acta Crystallogr E Crystallogr Commun Research Communications In the title salt, [Eu(C(3)H(7)NO)(8)][PMo(12)O(40)], the asymmetric unit comprises one α-Keggin-type [PMo(12)O(40)](3−) polyoxidometalate anion and one distorted dodeca­hedral [Eu(C(3)H(7)NO)(8)](3+) complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexa­gonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H⋯O hydrogen-bonding inter­actions, leading to the formation of a three-dimensional network structure. International Union of Crystallography 2016-03-04 /pmc/articles/PMC4910337/ /pubmed/27375861 http://dx.doi.org/10.1107/S2056989016003546 Text en © Ghandour et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ghandour, Yassine
Hammami, Imen
Najmudin, Shabir
Bonifácio, Cecilia
Belkhiria, Mohamed Salah
Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title_full Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title_fullStr Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title_full_unstemmed Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title_short Crystal structure of octa­kis­(N,N-di­methyl­formamide-κO)europium(III) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(VI)
title_sort crystal structure of octa­kis­(n,n-di­methyl­formamide-κo)europium(iii) tetra­cosa-μ(2)-oxido-dodeca­oxido-μ(12)-phosphato-dodeca­molybdate(vi)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910337/
https://www.ncbi.nlm.nih.gov/pubmed/27375861
http://dx.doi.org/10.1107/S2056989016003546
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