Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate

The asymmetric unit of the title compound, 2C(6)H(9)N(2) (+)·HPO(4) (2−), comprises two 2-amino­anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO(4) (2−) dianions are linked by O—H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations...

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Detalles Bibliográficos
Autores principales: Ittyachan, Reena, Ahigna, Melesuparambil Sundaram, Jagan, Rajamony
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910340/
https://www.ncbi.nlm.nih.gov/pubmed/27375882
http://dx.doi.org/10.1107/S2056989016004709
Descripción
Sumario:The asymmetric unit of the title compound, 2C(6)H(9)N(2) (+)·HPO(4) (2−), comprises two 2-amino­anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO(4) (2−) dianions are linked by O—H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations are linked by N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network extending parallel to (001).

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