Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate

The asymmetric unit of the title compound, 2C(6)H(9)N(2) (+)·HPO(4) (2−), comprises two 2-amino­anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO(4) (2−) dianions are linked by O—H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations...

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Autores principales: Ittyachan, Reena, Ahigna, Melesuparambil Sundaram, Jagan, Rajamony
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910340/
https://www.ncbi.nlm.nih.gov/pubmed/27375882
http://dx.doi.org/10.1107/S2056989016004709
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author Ittyachan, Reena
Ahigna, Melesuparambil Sundaram
Jagan, Rajamony
author_facet Ittyachan, Reena
Ahigna, Melesuparambil Sundaram
Jagan, Rajamony
author_sort Ittyachan, Reena
collection PubMed
description The asymmetric unit of the title compound, 2C(6)H(9)N(2) (+)·HPO(4) (2−), comprises two 2-amino­anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO(4) (2−) dianions are linked by O—H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations are linked by N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network extending parallel to (001).
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spelling pubmed-49103402016-07-01 Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate Ittyachan, Reena Ahigna, Melesuparambil Sundaram Jagan, Rajamony Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, 2C(6)H(9)N(2) (+)·HPO(4) (2−), comprises two 2-amino­anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO(4) (2−) dianions are linked by O—H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations are linked by N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional supra­molecular network extending parallel to (001). International Union of Crystallography 2016-03-22 /pmc/articles/PMC4910340/ /pubmed/27375882 http://dx.doi.org/10.1107/S2056989016004709 Text en © Ittyachan et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ittyachan, Reena
Ahigna, Melesuparambil Sundaram
Jagan, Rajamony
Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title_full Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title_fullStr Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title_full_unstemmed Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title_short Crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
title_sort crystal structure of bis­(2-amino­anilinium) hydrogen phosphate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910340/
https://www.ncbi.nlm.nih.gov/pubmed/27375882
http://dx.doi.org/10.1107/S2056989016004709
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