Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network

In the title compound, C(8)H(8)N(6), two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each mol­ecule forms four N—H⋯N hydrogen bonds with two...

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Autores principales: Lee, Chia-Hwa, Lee, Gene-Hsiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910350/
https://www.ncbi.nlm.nih.gov/pubmed/27375888
http://dx.doi.org/10.1107/S2056989016004497
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author Lee, Chia-Hwa
Lee, Gene-Hsiang
author_facet Lee, Chia-Hwa
Lee, Gene-Hsiang
author_sort Lee, Chia-Hwa
collection PubMed
description In the title compound, C(8)H(8)N(6), two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each mol­ecule forms four N—H⋯N hydrogen bonds with two neighbouring mol­ecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.
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spelling pubmed-49103502016-07-01 Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network Lee, Chia-Hwa Lee, Gene-Hsiang Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(8)H(8)N(6), two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each mol­ecule forms four N—H⋯N hydrogen bonds with two neighbouring mol­ecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction. International Union of Crystallography 2016-03-31 /pmc/articles/PMC4910350/ /pubmed/27375888 http://dx.doi.org/10.1107/S2056989016004497 Text en © Lee and Lee 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Lee, Chia-Hwa
Lee, Gene-Hsiang
Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_full Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_fullStr Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_full_unstemmed Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_short Crystal structure of 1,2-bis­[(1H-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
title_sort crystal structure of 1,2-bis­[(1h-imidazol-2-yl)methylidene]hydrazine and its one-dimensional hydrogen-bonding network
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910350/
https://www.ncbi.nlm.nih.gov/pubmed/27375888
http://dx.doi.org/10.1107/S2056989016004497
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