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Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate
In the crystal of the title compound, C(16)H(9)BrN(2)O(4)·0.5C(6)H(6), the molecules stack in a centrosymmetric unit cell in a 2:1 stoichiometry with co-crystallized benzene solvent molecules and interact via various weak interactions. This induces a geometry different from that predicted by the...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910353/ https://www.ncbi.nlm.nih.gov/pubmed/27375897 http://dx.doi.org/10.1107/S2056989016005120 |
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| author | Meany, Joseph E. Gerlach, Deidra L. Papish, Elizabeth T. Woski, Stephen A. |
| author_facet | Meany, Joseph E. Gerlach, Deidra L. Papish, Elizabeth T. Woski, Stephen A. |
| author_sort | Meany, Joseph E. |
| collection | PubMed |
| description | In the crystal of the title compound, C(16)H(9)BrN(2)O(4)·0.5C(6)H(6), the molecules stack in a centrosymmetric unit cell in a 2:1 stoichiometry with co-crystallized benzene solvent molecules and interact via various weak interactions. This induces a geometry different from that predicted by theory, and is unique among the hemibiquinones heretofore reported. |
| format | Online Article Text |
| id | pubmed-4910353 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-49103532016-07-01 Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate Meany, Joseph E. Gerlach, Deidra L. Papish, Elizabeth T. Woski, Stephen A. Acta Crystallogr E Crystallogr Commun Research Communications In the crystal of the title compound, C(16)H(9)BrN(2)O(4)·0.5C(6)H(6), the molecules stack in a centrosymmetric unit cell in a 2:1 stoichiometry with co-crystallized benzene solvent molecules and interact via various weak interactions. This induces a geometry different from that predicted by theory, and is unique among the hemibiquinones heretofore reported. International Union of Crystallography 2016-03-31 /pmc/articles/PMC4910353/ /pubmed/27375897 http://dx.doi.org/10.1107/S2056989016005120 Text en © Meany et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Meany, Joseph E. Gerlach, Deidra L. Papish, Elizabeth T. Woski, Stephen A. Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title | Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title_full | Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title_fullStr | Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title_full_unstemmed | Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title_short | Crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [BrHBQ(CN)(2)] benzene hemisolvate |
| title_sort | crystal structure of 4′-bromo-2′,5′-dimethoxy-2,5-dioxo-[1,1′-biphenyl]-3,4-dicarbonitrile [brhbq(cn)(2)] benzene hemisolvate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4910353/ https://www.ncbi.nlm.nih.gov/pubmed/27375897 http://dx.doi.org/10.1107/S2056989016005120 |
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