Cargando…
Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
[Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton locali...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2016
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4918963/ https://www.ncbi.nlm.nih.gov/pubmed/27105355 http://dx.doi.org/10.1021/acs.nanolett.5b04901 |
_version_ | 1782439186374066176 |
---|---|
author | Hofmann, Matthias S. Noé, Jonathan Kneer, Alexander Crochet, Jared J. Högele, Alexander |
author_facet | Hofmann, Matthias S. Noé, Jonathan Kneer, Alexander Crochet, Jared J. Högele, Alexander |
author_sort | Hofmann, Matthias S. |
collection | PubMed |
description | [Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton localization. Moreover, we quantify the energy scale of exciton localization potentials as ranging from a few to a few tens of millielectronvolts and stemming from both environmental disorder and shallow covalent side-wall defects. Our results establish disorder-induced crossover from the diffusive to the localized regime of nanotube excitons at cryogenic temperatures as a ubiquitous phenomenon in micelle-encapsulated and as-grown carbon nanotubes. |
format | Online Article Text |
id | pubmed-4918963 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-49189632016-06-24 Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes Hofmann, Matthias S. Noé, Jonathan Kneer, Alexander Crochet, Jared J. Högele, Alexander Nano Lett [Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton localization. Moreover, we quantify the energy scale of exciton localization potentials as ranging from a few to a few tens of millielectronvolts and stemming from both environmental disorder and shallow covalent side-wall defects. Our results establish disorder-induced crossover from the diffusive to the localized regime of nanotube excitons at cryogenic temperatures as a ubiquitous phenomenon in micelle-encapsulated and as-grown carbon nanotubes. American Chemical Society 2016-04-22 2016-05-11 /pmc/articles/PMC4918963/ /pubmed/27105355 http://dx.doi.org/10.1021/acs.nanolett.5b04901 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Hofmann, Matthias S. Noé, Jonathan Kneer, Alexander Crochet, Jared J. Högele, Alexander Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes |
title | Ubiquity of
Exciton Localization in Cryogenic Carbon Nanotubes |
title_full | Ubiquity of
Exciton Localization in Cryogenic Carbon Nanotubes |
title_fullStr | Ubiquity of
Exciton Localization in Cryogenic Carbon Nanotubes |
title_full_unstemmed | Ubiquity of
Exciton Localization in Cryogenic Carbon Nanotubes |
title_short | Ubiquity of
Exciton Localization in Cryogenic Carbon Nanotubes |
title_sort | ubiquity of
exciton localization in cryogenic carbon nanotubes |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4918963/ https://www.ncbi.nlm.nih.gov/pubmed/27105355 http://dx.doi.org/10.1021/acs.nanolett.5b04901 |
work_keys_str_mv | AT hofmannmatthiass ubiquityofexcitonlocalizationincryogeniccarbonnanotubes AT noejonathan ubiquityofexcitonlocalizationincryogeniccarbonnanotubes AT kneeralexander ubiquityofexcitonlocalizationincryogeniccarbonnanotubes AT crochetjaredj ubiquityofexcitonlocalizationincryogeniccarbonnanotubes AT hogelealexander ubiquityofexcitonlocalizationincryogeniccarbonnanotubes |