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Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes

[Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton locali...

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Autores principales: Hofmann, Matthias S., Noé, Jonathan, Kneer, Alexander, Crochet, Jared J., Högele, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4918963/
https://www.ncbi.nlm.nih.gov/pubmed/27105355
http://dx.doi.org/10.1021/acs.nanolett.5b04901
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author Hofmann, Matthias S.
Noé, Jonathan
Kneer, Alexander
Crochet, Jared J.
Högele, Alexander
author_facet Hofmann, Matthias S.
Noé, Jonathan
Kneer, Alexander
Crochet, Jared J.
Högele, Alexander
author_sort Hofmann, Matthias S.
collection PubMed
description [Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton localization. Moreover, we quantify the energy scale of exciton localization potentials as ranging from a few to a few tens of millielectronvolts and stemming from both environmental disorder and shallow covalent side-wall defects. Our results establish disorder-induced crossover from the diffusive to the localized regime of nanotube excitons at cryogenic temperatures as a ubiquitous phenomenon in micelle-encapsulated and as-grown carbon nanotubes.
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spelling pubmed-49189632016-06-24 Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes Hofmann, Matthias S. Noé, Jonathan Kneer, Alexander Crochet, Jared J. Högele, Alexander Nano Lett [Image: see text] We present photoluminescence studies of individual semiconducting single-wall carbon nanotubes at room and cryogenic temperatures. From the analysis of spatial and spectral features of nanotube photoluminescence, we identify characteristic signatures of unintentional exciton localization. Moreover, we quantify the energy scale of exciton localization potentials as ranging from a few to a few tens of millielectronvolts and stemming from both environmental disorder and shallow covalent side-wall defects. Our results establish disorder-induced crossover from the diffusive to the localized regime of nanotube excitons at cryogenic temperatures as a ubiquitous phenomenon in micelle-encapsulated and as-grown carbon nanotubes. American Chemical Society 2016-04-22 2016-05-11 /pmc/articles/PMC4918963/ /pubmed/27105355 http://dx.doi.org/10.1021/acs.nanolett.5b04901 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Hofmann, Matthias S.
Noé, Jonathan
Kneer, Alexander
Crochet, Jared J.
Högele, Alexander
Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title_full Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title_fullStr Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title_full_unstemmed Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title_short Ubiquity of Exciton Localization in Cryogenic Carbon Nanotubes
title_sort ubiquity of exciton localization in cryogenic carbon nanotubes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4918963/
https://www.ncbi.nlm.nih.gov/pubmed/27105355
http://dx.doi.org/10.1021/acs.nanolett.5b04901
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