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Anion-π Enzymes
[Image: see text] In this report, we introduce artificial enzymes that operate with anion-π interactions, an interaction that is essentially new to nature. The possibility to stabilize anionic intermediates and transition states on an π-acidic surface has been recently demonstrated, using the additi...
Autores principales: | Cotelle, Yoann, Lebrun, Vincent, Sakai, Naomi, Ward, Thomas R., Matile, Stefan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4919773/ https://www.ncbi.nlm.nih.gov/pubmed/27413782 http://dx.doi.org/10.1021/acscentsci.6b00097 |
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