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Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Linear two-coordinate copper complexes of cyclic (alkyl)(amino)carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4–300 K and occurs ver...

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Detalles Bibliográficos
Autores principales: Romanov, Alexander S., Di, Dawei, Yang, Le, Fernandez-Cestau, Julio, Becker, Ciaran R., James, Charlotte E., Zhu, Bonan, Linnolahti, Mikko, Credgington, Dan, Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4920075/
https://www.ncbi.nlm.nih.gov/pubmed/27087532
http://dx.doi.org/10.1039/c6cc02349e