Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers

The host-guest complexes of conjugated microporous polymers encapsulating C(60) and dye molecules have been investigated systematically. The orientation of guest molecules inside the cavities, have different terms: inside the open cavities of the polymer, or inside the cavities formed by packing dif...

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Detalles Bibliográficos
Autores principales: Xu, Lai, Li, Youyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4928063/
https://www.ncbi.nlm.nih.gov/pubmed/27356483
http://dx.doi.org/10.1038/srep28784
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author Xu, Lai
Li, Youyong
author_facet Xu, Lai
Li, Youyong
author_sort Xu, Lai
collection PubMed
description The host-guest complexes of conjugated microporous polymers encapsulating C(60) and dye molecules have been investigated systematically. The orientation of guest molecules inside the cavities, have different terms: inside the open cavities of the polymer, or inside the cavities formed by packing different polymers. The host backbone shows responsive dynamic behavior in order to accommodate the size and shape of incoming guest molecule or guest aggregates. Simulations show that the host-guest binding of conjugated polymers is stronger than that of non-conjugated polymers. This detailed study could provide a clear picture for the host-guest interaction for dynamic conjugated microporous polymers. The mechanism obtained could guide designing new conjugated microporous polymers.
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spelling pubmed-49280632016-07-01 Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers Xu, Lai Li, Youyong Sci Rep Article The host-guest complexes of conjugated microporous polymers encapsulating C(60) and dye molecules have been investigated systematically. The orientation of guest molecules inside the cavities, have different terms: inside the open cavities of the polymer, or inside the cavities formed by packing different polymers. The host backbone shows responsive dynamic behavior in order to accommodate the size and shape of incoming guest molecule or guest aggregates. Simulations show that the host-guest binding of conjugated polymers is stronger than that of non-conjugated polymers. This detailed study could provide a clear picture for the host-guest interaction for dynamic conjugated microporous polymers. The mechanism obtained could guide designing new conjugated microporous polymers. Nature Publishing Group 2016-06-30 /pmc/articles/PMC4928063/ /pubmed/27356483 http://dx.doi.org/10.1038/srep28784 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Xu, Lai
Li, Youyong
Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title_full Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title_fullStr Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title_full_unstemmed Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title_short Responsive Guest Encapsulation of Dynamic Conjugated Microporous Polymers
title_sort responsive guest encapsulation of dynamic conjugated microporous polymers
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4928063/
https://www.ncbi.nlm.nih.gov/pubmed/27356483
http://dx.doi.org/10.1038/srep28784
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AT liyouyong responsiveguestencapsulationofdynamicconjugatedmicroporouspolymers

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