Data on the identification and characterization of by-products from N-Cbz-3-aminopropanal and t-BuOOH/H(2)O(2) chemical reaction in chloroperoxidase-catalyzed oxidations

This data article is related to the subject of a publication in Process Biochemistry, entitled “Chloroperoxidase-catalyzed amino alcohol oxidation: Substrate specificity and novel strategy for the synthesis of N-Cbz-3-aminopropanal” (Masdeu et al., 2016) [1]. Here, the products of the chemical react...

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Detalles Bibliográficos
Autores principales: Masdeu, Gerard, Pérez-Trujillo, Míriam, López-Santín, Josep, Álvaro, Gregorio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2016
Materias:
Data Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4939320/
https://www.ncbi.nlm.nih.gov/pubmed/27437440
http://dx.doi.org/10.1016/j.dib.2016.06.028
Descripción
Sumario:This data article is related to the subject of a publication in Process Biochemistry, entitled “Chloroperoxidase-catalyzed amino alcohol oxidation: Substrate specificity and novel strategy for the synthesis of N-Cbz-3-aminopropanal” (Masdeu et al., 2016) [1]. Here, the products of the chemical reaction involving the amino aldehyde (N-Cbz-3-aminopropanal) and peroxides (tert-butyl hydroperoxide and H(2)O(2)) are characterized by NMR. (1)H and (13)C NMR full characterization of the products was obtained based on 2D NMR, 1D selective NOESY and diffusion spectroscopy (DOSY) experiments.

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