Application of a new HPLC-ICP-MS method for simultaneous determination of Al(3+) and aluminium fluoride complexes

The paper presents the new HPLC-ICP-MS method used for conducting speciation analysis of aluminum as free Al(3+) and aluminum fluoride complexes during one analysis. In the study, 5% HNO(3) was used as a derivative reagent in order to minimize the possibility of clogging the torch in ICP-MS. Using t...

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Detalles Bibliográficos
Autores principales: Zioła-Frankowska, Anetta, Kuta, Jan, Frankowski, Marcin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4939753/
https://www.ncbi.nlm.nih.gov/pubmed/27441221
http://dx.doi.org/10.1016/j.heliyon.2015.e00035
Descripción
Sumario:The paper presents the new HPLC-ICP-MS method used for conducting speciation analysis of aluminum as free Al(3+) and aluminum fluoride complexes during one analysis. In the study, 5% HNO(3) was used as a derivative reagent in order to minimize the possibility of clogging the torch in ICP-MS. Using the new HPLC-ICP-MS method, speciation analysis of aluminum and aluminum fluoride complexes was conducted on the basis of model solutions and real samples (soil-water extracts and groundwater samples). The analysis in the presented analytical system lasts only 4 min.

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