Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations

Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with [Image: see text]. These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measure...

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Detalles Bibliográficos
Autores principales: Chen, Xiaoyu, Gao, Feng, Yang, Wuqin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4941407/
https://www.ncbi.nlm.nih.gov/pubmed/27403720
http://dx.doi.org/10.1038/srep29314
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author Chen, Xiaoyu
Gao, Feng
Yang, Wuqin
author_facet Chen, Xiaoyu
Gao, Feng
Yang, Wuqin
author_sort Chen, Xiaoyu
collection PubMed
description Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with [Image: see text]. These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive π-stacking radical cation with single phenyl ring and reveals their conductivity has relationship with the stack structure which affected by the substituent.
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spelling pubmed-49414072016-07-20 Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations Chen, Xiaoyu Gao, Feng Yang, Wuqin Sci Rep Article Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with [Image: see text]. These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive π-stacking radical cation with single phenyl ring and reveals their conductivity has relationship with the stack structure which affected by the substituent. Nature Publishing Group 2016-07-11 /pmc/articles/PMC4941407/ /pubmed/27403720 http://dx.doi.org/10.1038/srep29314 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Chen, Xiaoyu
Gao, Feng
Yang, Wuqin
Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title_full Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title_fullStr Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title_full_unstemmed Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title_short Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations
title_sort single-crystal x-ray structures of conductive π-stacking dimers of tetrakis(alkylthio)benzene radical cations
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4941407/
https://www.ncbi.nlm.nih.gov/pubmed/27403720
http://dx.doi.org/10.1038/srep29314
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AT yangwuqin singlecrystalxraystructuresofconductivepstackingdimersoftetrakisalkylthiobenzeneradicalcations

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