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Turning Cucurbit[8]uril into a Supramolecular Nanoreactor for Asymmetric Catalysis
Chiral macromolecules have been widely used as synthetic pockets to mimic natural enzymes and promote asymmetric reactions. An achiral host, cucurbit[8]uril (CB[8]), was used for an asymmetric Lewis acid catalyzed Diels–Alder reaction. We achieved a remarkable increase in enantioselectivity and a la...
Autores principales: | Zheng, Lifei, Sonzini, Silvia, Ambarwati, Masyitha, Rosta, Edina, Scherman, Oren A., Herrmann, Andreas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY‐VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955226/ https://www.ncbi.nlm.nih.gov/pubmed/27478269 http://dx.doi.org/10.1002/ange.201505628 |
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