Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates

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Fe(III)–hypohalite complexes have been implicated in a wide range of important enzyme‐catalyzed halogenation reactions including the biosynthesis of natural products and antibiotics and post‐translational modification of proteins. The absence of spectroscopic data on such species precludes their ide...

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Detalles Bibliográficos
Autores principales: Draksharapu, Apparao, Angelone, Davide, Quesne, Matthew G., Padamati, Sandeep K., Gómez, Laura, Hage, Ronald, Costas, Miquel, Browne, Wesley R., de Visser, Sam P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Zuschriften
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4955228/
https://www.ncbi.nlm.nih.gov/pubmed/27478260
http://dx.doi.org/10.1002/ange.201411995
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