A fast electrochromic polymer based on TEMPO substituted polytriphenylamine

A novel strategy to obtain rapid electrochromic switching response by introducing 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) moiety into polytriphenylamine backbone has been developed. The electrochromic properties of the integrated polymer film are investigated and a possible mechanism is propose...

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Detalles Bibliográficos
Autores principales: Ji, Lvlv, Dai, Yuyu, Yan, Shuanma, Lv, Xiaojing, Su, Chang, Xu, Lihuan, Lv, Yaokang, Ouyang, Mi, Chen, Zuofeng, Zhang, Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4957116/
https://www.ncbi.nlm.nih.gov/pubmed/27444398
http://dx.doi.org/10.1038/srep30068
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author Ji, Lvlv
Dai, Yuyu
Yan, Shuanma
Lv, Xiaojing
Su, Chang
Xu, Lihuan
Lv, Yaokang
Ouyang, Mi
Chen, Zuofeng
Zhang, Cheng
author_facet Ji, Lvlv
Dai, Yuyu
Yan, Shuanma
Lv, Xiaojing
Su, Chang
Xu, Lihuan
Lv, Yaokang
Ouyang, Mi
Chen, Zuofeng
Zhang, Cheng
author_sort Ji, Lvlv
collection PubMed
description A novel strategy to obtain rapid electrochromic switching response by introducing 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) moiety into polytriphenylamine backbone has been developed. The electrochromic properties of the integrated polymer film are investigated and a possible mechanism is proposed with TEMPO as a counterion-reservoir group to rapidly balance the charges during electrochromic switching, which leads to significantly improved electrochromism performance.
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spelling pubmed-49571162016-07-26 A fast electrochromic polymer based on TEMPO substituted polytriphenylamine Ji, Lvlv Dai, Yuyu Yan, Shuanma Lv, Xiaojing Su, Chang Xu, Lihuan Lv, Yaokang Ouyang, Mi Chen, Zuofeng Zhang, Cheng Sci Rep Article A novel strategy to obtain rapid electrochromic switching response by introducing 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) moiety into polytriphenylamine backbone has been developed. The electrochromic properties of the integrated polymer film are investigated and a possible mechanism is proposed with TEMPO as a counterion-reservoir group to rapidly balance the charges during electrochromic switching, which leads to significantly improved electrochromism performance. Nature Publishing Group 2016-07-22 /pmc/articles/PMC4957116/ /pubmed/27444398 http://dx.doi.org/10.1038/srep30068 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Ji, Lvlv
Dai, Yuyu
Yan, Shuanma
Lv, Xiaojing
Su, Chang
Xu, Lihuan
Lv, Yaokang
Ouyang, Mi
Chen, Zuofeng
Zhang, Cheng
A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title_full A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title_fullStr A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title_full_unstemmed A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title_short A fast electrochromic polymer based on TEMPO substituted polytriphenylamine
title_sort fast electrochromic polymer based on tempo substituted polytriphenylamine
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4957116/
https://www.ncbi.nlm.nih.gov/pubmed/27444398
http://dx.doi.org/10.1038/srep30068
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