Coherent optical phonon oscillation and possible electronic softening in WTe(2) crystals

A rapidly-growing interest in WTe(2) has been triggered by the giant magnetoresistance effect discovered in this unique system. While many efforts have been made towards uncovering the electron- and spin-relevant mechanisms, the role of lattice vibration remains poorly understood. Here, we study the coherent vibrational dynamics in WTe(2) crystals by using ultrafast pump-probe spectroscopy. The oscillation signal in time domain in WTe(2) has been ascribed as due to the coherent dynamics of the lowest energy A(1) optical phonons with polarization- and wavelength-dependent measurements. With increasing temperature, the phonon energy decreases due to anharmonic decay of the optical phonons into acoustic phonons. Moreover, a significant drop (15%) of the phonon energy with increasing pump power is observed which is possibly caused by the lattice anharmonicity induced by electronic excitation and phonon-phonon interaction.