(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H(2)O employing H(2)O(2) as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e....

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Detalles Bibliográficos
Autores principales: Ballistreri, Francesco Paolo, Gangemi, Chiara M. A., Pappalardo, Andrea, Tomaselli, Gaetano A., Toscano, Rosa Maria, Trusso Sfrazzetto, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4964487/
https://www.ncbi.nlm.nih.gov/pubmed/27420047
http://dx.doi.org/10.3390/ijms17071112
Descripción
Sumario:Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H(2)O employing H(2)O(2) as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).

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