(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H(2)O employing H(2)O(2) as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e....

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Autores principales: Ballistreri, Francesco Paolo, Gangemi, Chiara M. A., Pappalardo, Andrea, Tomaselli, Gaetano A., Toscano, Rosa Maria, Trusso Sfrazzetto, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4964487/
https://www.ncbi.nlm.nih.gov/pubmed/27420047
http://dx.doi.org/10.3390/ijms17071112
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author Ballistreri, Francesco Paolo
Gangemi, Chiara M. A.
Pappalardo, Andrea
Tomaselli, Gaetano A.
Toscano, Rosa Maria
Trusso Sfrazzetto, Giuseppe
author_facet Ballistreri, Francesco Paolo
Gangemi, Chiara M. A.
Pappalardo, Andrea
Tomaselli, Gaetano A.
Toscano, Rosa Maria
Trusso Sfrazzetto, Giuseppe
author_sort Ballistreri, Francesco Paolo
collection PubMed
description Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H(2)O employing H(2)O(2) as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
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spelling pubmed-49644872016-08-03 (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol Ballistreri, Francesco Paolo Gangemi, Chiara M. A. Pappalardo, Andrea Tomaselli, Gaetano A. Toscano, Rosa Maria Trusso Sfrazzetto, Giuseppe Int J Mol Sci Communication Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H(2)O employing H(2)O(2) as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%). MDPI 2016-07-12 /pmc/articles/PMC4964487/ /pubmed/27420047 http://dx.doi.org/10.3390/ijms17071112 Text en © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Ballistreri, Francesco Paolo
Gangemi, Chiara M. A.
Pappalardo, Andrea
Tomaselli, Gaetano A.
Toscano, Rosa Maria
Trusso Sfrazzetto, Giuseppe
(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_full (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_fullStr (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_full_unstemmed (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_short (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
title_sort (salen)mn(iii) catalyzed asymmetric epoxidation reactions by hydrogen peroxide in water: a green protocol
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4964487/
https://www.ncbi.nlm.nih.gov/pubmed/27420047
http://dx.doi.org/10.3390/ijms17071112
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