The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile

Cyclic voltammetry of silver coordination complexes in acetonitrile and in a single-phase supercritical carbon dioxide/acetonitrile (scCO(2)/CH(3)CN) system is reported. Five silver precursors are investigated: (1,5-cyclooctadiene)(hexafluoroacetylacetonato) silver(I) [Ag(hfac)(COD)], (hexafluoroace...

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Autores principales: Bartlett, Philip N, Perdjon-Abel, Magdalena, Cook, David, Reid, Gillian, Levason, William, Cheng, Fei, Zhang, Wenjian, George, Michael W, Ke, Jie, Beanland, Richard, Sloan, Jeremy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4964882/
http://dx.doi.org/10.1002/celc.201300131
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author Bartlett, Philip N
Perdjon-Abel, Magdalena
Cook, David
Reid, Gillian
Levason, William
Cheng, Fei
Zhang, Wenjian
George, Michael W
Ke, Jie
Beanland, Richard
Sloan, Jeremy
author_facet Bartlett, Philip N
Perdjon-Abel, Magdalena
Cook, David
Reid, Gillian
Levason, William
Cheng, Fei
Zhang, Wenjian
George, Michael W
Ke, Jie
Beanland, Richard
Sloan, Jeremy
author_sort Bartlett, Philip N
collection PubMed
description Cyclic voltammetry of silver coordination complexes in acetonitrile and in a single-phase supercritical carbon dioxide/acetonitrile (scCO(2)/CH(3)CN) system is reported. Five silver precursors are investigated: (1,5-cyclooctadiene)(hexafluoroacetylacetonato) silver(I) [Ag(hfac)(COD)], (hexafluoroacetylacetonato)(triphenylphosphine) silver(I) [Ag(hfac)(PPh(3))], (perfluorooctanoato)bis(triphenylphosphine) silver(I) [Ag(CF(3)(CF(2))(6)CO(2))(PPh(3))(2)], tetrakis(triphenylphosphine) silver(I) tetrafluoroborate [Ag(PPh(3))(4)][BF(4)] and tetrakis(acetonitrile) silver(I) tetrafluoroborate [Ag(CH(3)CN)(4)][BF(4)]. Of these, [Ag(CH(3)CN)(4)][BF(4)] is found to be the most suitable for electrodeposition of silver from scCO(2)/CH(3)CN.
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spelling pubmed-49648822016-08-11 The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile Bartlett, Philip N Perdjon-Abel, Magdalena Cook, David Reid, Gillian Levason, William Cheng, Fei Zhang, Wenjian George, Michael W Ke, Jie Beanland, Richard Sloan, Jeremy ChemElectroChem Articles Cyclic voltammetry of silver coordination complexes in acetonitrile and in a single-phase supercritical carbon dioxide/acetonitrile (scCO(2)/CH(3)CN) system is reported. Five silver precursors are investigated: (1,5-cyclooctadiene)(hexafluoroacetylacetonato) silver(I) [Ag(hfac)(COD)], (hexafluoroacetylacetonato)(triphenylphosphine) silver(I) [Ag(hfac)(PPh(3))], (perfluorooctanoato)bis(triphenylphosphine) silver(I) [Ag(CF(3)(CF(2))(6)CO(2))(PPh(3))(2)], tetrakis(triphenylphosphine) silver(I) tetrafluoroborate [Ag(PPh(3))(4)][BF(4)] and tetrakis(acetonitrile) silver(I) tetrafluoroborate [Ag(CH(3)CN)(4)][BF(4)]. Of these, [Ag(CH(3)CN)(4)][BF(4)] is found to be the most suitable for electrodeposition of silver from scCO(2)/CH(3)CN. WILEY-VCH Verlag 2014-01-03 2013-11-26 /pmc/articles/PMC4964882/ http://dx.doi.org/10.1002/celc.201300131 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited https://creativecommons.org/licenses/by/4.0/ © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited
spellingShingle Articles
Bartlett, Philip N
Perdjon-Abel, Magdalena
Cook, David
Reid, Gillian
Levason, William
Cheng, Fei
Zhang, Wenjian
George, Michael W
Ke, Jie
Beanland, Richard
Sloan, Jeremy
The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title_full The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title_fullStr The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title_full_unstemmed The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title_short The Electrodeposition of Silver from Supercritical Carbon Dioxide/Acetonitrile
title_sort electrodeposition of silver from supercritical carbon dioxide/acetonitrile
topic Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4964882/
http://dx.doi.org/10.1002/celc.201300131
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