Cargando…

Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods

Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H(2)O(2)), based on the prepared ZnO NRs, was examined through the use of current-voltage measuremen...

Descripción completa

Detalles Bibliográficos
Autores principales: Al-Hardan, Naif H., Abdul Hamid, Muhammad Azmi, Shamsudin, Roslinda, Othman, Norinsan Kamil, Kar Keng, Lim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4970054/
https://www.ncbi.nlm.nih.gov/pubmed/27367693
http://dx.doi.org/10.3390/s16071004
_version_ 1782445901585842176
author Al-Hardan, Naif H.
Abdul Hamid, Muhammad Azmi
Shamsudin, Roslinda
Othman, Norinsan Kamil
Kar Keng, Lim
author_facet Al-Hardan, Naif H.
Abdul Hamid, Muhammad Azmi
Shamsudin, Roslinda
Othman, Norinsan Kamil
Kar Keng, Lim
author_sort Al-Hardan, Naif H.
collection PubMed
description Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H(2)O(2)), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements. The measured currents, as a function of H(2)O(2) concentrations ranging from 10 μM to 700 μM, revealed two distinct behaviours and good performance, with a lower detection limit (LOD) of 42 μM for the low range of H(2)O(2) concentrations (first region), and a LOD of 143.5 μM for the higher range of H(2)O(2) concentrations (second region). The prepared ZnO NRs show excellent electrocatalytic activity. This enables a measurable and stable output current. The results were correlated with the oxidation process of the H(2)O(2) and revealed a good performance for the ZnO NR non-enzymatic H(2)O(2) sensor.
format Online
Article
Text
id pubmed-4970054
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-49700542016-08-04 Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods Al-Hardan, Naif H. Abdul Hamid, Muhammad Azmi Shamsudin, Roslinda Othman, Norinsan Kamil Kar Keng, Lim Sensors (Basel) Article Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H(2)O(2)), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements. The measured currents, as a function of H(2)O(2) concentrations ranging from 10 μM to 700 μM, revealed two distinct behaviours and good performance, with a lower detection limit (LOD) of 42 μM for the low range of H(2)O(2) concentrations (first region), and a LOD of 143.5 μM for the higher range of H(2)O(2) concentrations (second region). The prepared ZnO NRs show excellent electrocatalytic activity. This enables a measurable and stable output current. The results were correlated with the oxidation process of the H(2)O(2) and revealed a good performance for the ZnO NR non-enzymatic H(2)O(2) sensor. MDPI 2016-06-29 /pmc/articles/PMC4970054/ /pubmed/27367693 http://dx.doi.org/10.3390/s16071004 Text en © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Al-Hardan, Naif H.
Abdul Hamid, Muhammad Azmi
Shamsudin, Roslinda
Othman, Norinsan Kamil
Kar Keng, Lim
Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_full Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_fullStr Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_full_unstemmed Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_short Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_sort amperometric non-enzymatic hydrogen peroxide sensor based on aligned zinc oxide nanorods
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4970054/
https://www.ncbi.nlm.nih.gov/pubmed/27367693
http://dx.doi.org/10.3390/s16071004
work_keys_str_mv AT alhardannaifh amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods
AT abdulhamidmuhammadazmi amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods
AT shamsudinroslinda amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods
AT othmannorinsankamil amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods
AT karkenglim amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods