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[μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2) N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis
The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two dithiocarbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-ylethylene (bpe) molecules and two acetonitrile solvent molecules. The full binuclear complex i...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971847/ https://www.ncbi.nlm.nih.gov/pubmed/27536388 http://dx.doi.org/10.1107/S2056989016010768 |
Sumario: | The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two dithiocarbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-ylethylene (bpe) molecules and two acetonitrile solvent molecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe molecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N(2)S(4) coordination geometry is based on an octahedron. Supramolecular layers, sustained by hydroxy-O—H⋯O(hydroxy) and hydroxy-O—H⋯N(bpe) hydrogen bonding, interpenetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the acetonitrile solvent molecules. Additional intermolecular interactions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π interactions. |
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