Cargando…
[μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2) N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis
The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two dithiocarbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-ylethylene (bpe) molecules and two acetonitrile solvent molecules. The full binuclear complex i...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971847/ https://www.ncbi.nlm.nih.gov/pubmed/27536388 http://dx.doi.org/10.1107/S2056989016010768 |
_version_ | 1782446173407150080 |
---|---|
author | Jotani, Mukesh M. Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. |
author_facet | Jotani, Mukesh M. Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. |
author_sort | Jotani, Mukesh M. |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two dithiocarbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-ylethylene (bpe) molecules and two acetonitrile solvent molecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe molecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N(2)S(4) coordination geometry is based on an octahedron. Supramolecular layers, sustained by hydroxy-O—H⋯O(hydroxy) and hydroxy-O—H⋯N(bpe) hydrogen bonding, interpenetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the acetonitrile solvent molecules. Additional intermolecular interactions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π interactions. |
format | Online Article Text |
id | pubmed-4971847 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-49718472016-08-17 [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2) N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis Jotani, Mukesh M. Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two dithiocarbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-ylethylene (bpe) molecules and two acetonitrile solvent molecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe molecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N(2)S(4) coordination geometry is based on an octahedron. Supramolecular layers, sustained by hydroxy-O—H⋯O(hydroxy) and hydroxy-O—H⋯N(bpe) hydrogen bonding, interpenetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the acetonitrile solvent molecules. Additional intermolecular interactions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π interactions. International Union of Crystallography 2016-07-12 /pmc/articles/PMC4971847/ /pubmed/27536388 http://dx.doi.org/10.1107/S2056989016010768 Text en © Jotani et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Jotani, Mukesh M. Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2) N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2) S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title | [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2)
N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title_full | [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2)
N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title_fullStr | [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2)
N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title_full_unstemmed | [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2)
N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title_short | [μ(2)-trans-1,2-Bis(pyridin-4-yl)ethene-κ(2)
N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ(2)
S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis |
title_sort | [μ(2)-trans-1,2-bis(pyridin-4-yl)ethene-κ(2)
n:n′]bis{[1,2-bis(pyridin-4-yl)ethene-κn]bis[n-(2-hydroxyethyl)-n-isopropyldithiocarbamato-κ(2)
s,s′]cadmium} acetonitrile tetrasolvate: crystal structure and hirshfeld surface analysis |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971847/ https://www.ncbi.nlm.nih.gov/pubmed/27536388 http://dx.doi.org/10.1107/S2056989016010768 |
work_keys_str_mv | AT jotanimukeshm m2trans12bispyridin4ylethenek2nnbis12bispyridin4yletheneknbisn2hydroxyethylnisopropyldithiocarbamatok2sscadmiumacetonitriletetrasolvatecrystalstructureandhirshfeldsurfaceanalysis AT poplaukhinpavel m2trans12bispyridin4ylethenek2nnbis12bispyridin4yletheneknbisn2hydroxyethylnisopropyldithiocarbamatok2sscadmiumacetonitriletetrasolvatecrystalstructureandhirshfeldsurfaceanalysis AT armanhadid m2trans12bispyridin4ylethenek2nnbis12bispyridin4yletheneknbisn2hydroxyethylnisopropyldithiocarbamatok2sscadmiumacetonitriletetrasolvatecrystalstructureandhirshfeldsurfaceanalysis AT tiekinkedwardrt m2trans12bispyridin4ylethenek2nnbis12bispyridin4yletheneknbisn2hydroxyethylnisopropyldithiocarbamatok2sscadmiumacetonitriletetrasolvatecrystalstructureandhirshfeldsurfaceanalysis |