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[μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis

The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two di­thio­carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl­ethyl­ene (bpe) mol­ecules and two aceto­nitrile solvent mol­ecules. The full binuclear complex i...

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Autores principales: Jotani, Mukesh M., Poplaukhin, Pavel, Arman, Hadi D., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971847/
https://www.ncbi.nlm.nih.gov/pubmed/27536388
http://dx.doi.org/10.1107/S2056989016010768
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author Jotani, Mukesh M.
Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
author_facet Jotani, Mukesh M.
Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
author_sort Jotani, Mukesh M.
collection PubMed
description The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two di­thio­carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl­ethyl­ene (bpe) mol­ecules and two aceto­nitrile solvent mol­ecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe mol­ecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N(2)S(4) coordination geometry is based on an octa­hedron. Supra­molecular layers, sustained by hy­droxy-O—H⋯O(hy­droxy) and hy­droxy-O—H⋯N(bpe) hydrogen bonding, inter­penetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the aceto­nitrile solvent mol­ecules. Additional inter­molecular inter­actions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π inter­actions.
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spelling pubmed-49718472016-08-17 [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis Jotani, Mukesh M. Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, [Cd(2)(C(12)H(10)N(2))(3)(C(6)H(12)NOS(2))(4)]·4C(2)H(3)N, comprises a Cd(II) atom, two di­thio­carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl­ethyl­ene (bpe) mol­ecules and two aceto­nitrile solvent mol­ecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe mol­ecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N(2)S(4) coordination geometry is based on an octa­hedron. Supra­molecular layers, sustained by hy­droxy-O—H⋯O(hy­droxy) and hy­droxy-O—H⋯N(bpe) hydrogen bonding, inter­penetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the aceto­nitrile solvent mol­ecules. Additional inter­molecular inter­actions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π inter­actions. International Union of Crystallography 2016-07-12 /pmc/articles/PMC4971847/ /pubmed/27536388 http://dx.doi.org/10.1107/S2056989016010768 Text en © Jotani et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Jotani, Mukesh M.
Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
[μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title_full [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title_fullStr [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title_full_unstemmed [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title_short [μ(2)-trans-1,2-Bis­(pyridin-4-yl)ethene-κ(2) N:N′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κN]bis­[N-(2-hydroxy­eth­yl)-N-iso­propyl­dithio­carbamato-κ(2) S,S′]cadmium} aceto­nitrile tetra­solvate: crystal structure and Hirshfeld surface analysis
title_sort [μ(2)-trans-1,2-bis­(pyridin-4-yl)ethene-κ(2) n:n′]bis­{[1,2-bis­(pyridin-4-yl)ethene-κn]bis­[n-(2-hydroxy­eth­yl)-n-iso­propyl­dithio­carbamato-κ(2) s,s′]cadmium} aceto­nitrile tetra­solvate: crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4971847/
https://www.ncbi.nlm.nih.gov/pubmed/27536388
http://dx.doi.org/10.1107/S2056989016010768
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